TY - JOUR
T1 - The Stark effect in the A1Σ+-X1Σ+(0, 0) band of barium monoxide, BaO
AU - Wang, Fang
AU - Steimle, Timothy
N1 - Funding Information:
This research has been supported by the National Science Foundation – Experimental Physical Chemistry (Grant No. 0646473 ). The authors would like to thank the Prof. William Klemperer (Harvard University) for helpful discussion and pointing out the typographical error in Table I of Ref. [4] .
PY - 2010/1/7
Y1 - 2010/1/7
N2 - The optical Stark spectrum of the A1Σ-X1Σ+(0, 0) band of BaO was recorded and analyzed to determine the permanent electric dipole moments, μ, for the A1Σ(ν = 0) and X1Σ+(ν = 0) states to be 3.125(16) D and 7.869(17) D, respectively. The molecular beam electric resonance data for the X1Σ+(ν = 0) states [L. Wharton, M. Kaufman, W. Klemperer, J. Chem. Phys. 37 (1962) 621] was re-analyzed to produce μ of 7.9530(4) D. The systematic difference between the MBER and optical Stark values is discussed.
AB - The optical Stark spectrum of the A1Σ-X1Σ+(0, 0) band of BaO was recorded and analyzed to determine the permanent electric dipole moments, μ, for the A1Σ(ν = 0) and X1Σ+(ν = 0) states to be 3.125(16) D and 7.869(17) D, respectively. The molecular beam electric resonance data for the X1Σ+(ν = 0) states [L. Wharton, M. Kaufman, W. Klemperer, J. Chem. Phys. 37 (1962) 621] was re-analyzed to produce μ of 7.9530(4) D. The systematic difference between the MBER and optical Stark values is discussed.
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U2 - 10.1016/j.cplett.2009.12.020
DO - 10.1016/j.cplett.2009.12.020
M3 - Article
AN - SCOPUS:72649098016
SN - 0009-2614
VL - 484
SP - 110
EP - 112
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 4-6
ER -