The Stark effect in the A1Σ+-X1Σ+(0, 0) band of barium monoxide, BaO

Fang Wang, Timothy Steimle

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Abstract

The optical Stark spectrum of the A1Σ-X1Σ+(0, 0) band of BaO was recorded and analyzed to determine the permanent electric dipole moments, μ, for the A1Σ(ν = 0) and X1Σ+(ν = 0) states to be 3.125(16) D and 7.869(17) D, respectively. The molecular beam electric resonance data for the X1Σ+(ν = 0) states [L. Wharton, M. Kaufman, W. Klemperer, J. Chem. Phys. 37 (1962) 621] was re-analyzed to produce μ of 7.9530(4) D. The systematic difference between the MBER and optical Stark values is discussed.

Original languageEnglish (US)
Pages (from-to)110-112
Number of pages3
JournalChemical Physics Letters
Volume484
Issue number4-6
DOIs
StatePublished - Jan 7 2010

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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