The pure rotational spectrum of platinum monocarbide, PtC

Chengbing Qin, Ruohan Zhang, Fang Wang, Timothy Steimle

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

The J = 1 ← J = 0 and J = 2 ← J = 1 rotational transitions of platinum monocarbide, PtC, have been recorded using the separated field pump/probe microwave optical double resonance technique and analyzed to determine the fine and hyperfine parameters for the X 1Σ +(v = 0) state. The 195Pt (I = 1/2) nuclear spin-rotation interaction parameter, CIeff, was determined to be +0.138(6) MHz. A comparison with other Pt-containing molecules and a proposed molecular orbital correlation diagram is given.

Original languageEnglish (US)
Pages (from-to)40-43
Number of pages4
JournalChemical Physics Letters
Volume535
DOIs
StatePublished - May 11 2012

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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