TY - JOUR
T1 - The pure rotational spectrum of platinum monocarbide, PtC
AU - Qin, Chengbing
AU - Zhang, Ruohan
AU - Wang, Fang
AU - Steimle, Timothy
N1 - Funding Information:
This research has been supported by a Grant from the Fundamental Interactions Branch, Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy ( DE-FG02-01ER15153-A003 ).
PY - 2012/5/11
Y1 - 2012/5/11
N2 - The J = 1 ← J = 0 and J = 2 ← J = 1 rotational transitions of platinum monocarbide, PtC, have been recorded using the separated field pump/probe microwave optical double resonance technique and analyzed to determine the fine and hyperfine parameters for the X 1Σ +(v = 0) state. The 195Pt (I = 1/2) nuclear spin-rotation interaction parameter, CIeff, was determined to be +0.138(6) MHz. A comparison with other Pt-containing molecules and a proposed molecular orbital correlation diagram is given.
AB - The J = 1 ← J = 0 and J = 2 ← J = 1 rotational transitions of platinum monocarbide, PtC, have been recorded using the separated field pump/probe microwave optical double resonance technique and analyzed to determine the fine and hyperfine parameters for the X 1Σ +(v = 0) state. The 195Pt (I = 1/2) nuclear spin-rotation interaction parameter, CIeff, was determined to be +0.138(6) MHz. A comparison with other Pt-containing molecules and a proposed molecular orbital correlation diagram is given.
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U2 - 10.1016/j.cplett.2012.03.058
DO - 10.1016/j.cplett.2012.03.058
M3 - Article
AN - SCOPUS:84860281991
SN - 0009-2614
VL - 535
SP - 40
EP - 43
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -