The permanent electric dipole moments of the X3Δ,E 3Π,A3Φ and B3Π states of titanium monoxide, TiO

Timothy Steimle, Wilton Virgo

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

The optical Stark spectrum of the origin bands of the E3Π0-X3Δ1,A3Φ 2-X3Δ1, and B3Π 0-X3Δ1 electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X3Δ1,E3Π0, A3Φ2 and B3Π0 states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.

Original languageEnglish (US)
Pages (from-to)30-36
Number of pages7
JournalChemical Physics Letters
Volume381
Issue number1-2
DOIs
StatePublished - Nov 4 2003

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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