TY - JOUR
T1 - The permanent electric dipole moments of the X3Δ,E 3Π,A3Φ and B3Π states of titanium monoxide, TiO
AU - Steimle, Timothy
AU - Virgo, Wilton
N1 - Funding Information:
This work was supported by a grant from the National Science Foundation – Experimental Physical Chemistry (CHE-0078899).
PY - 2003/11/4
Y1 - 2003/11/4
N2 - The optical Stark spectrum of the origin bands of the E3Π0-X3Δ1,A3Φ 2-X3Δ1, and B3Π 0-X3Δ1 electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X3Δ1,E3Π0, A3Φ2 and B3Π0 states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.
AB - The optical Stark spectrum of the origin bands of the E3Π0-X3Δ1,A3Φ 2-X3Δ1, and B3Π 0-X3Δ1 electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X3Δ1,E3Π0, A3Φ2 and B3Π0 states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.
UR - http://www.scopus.com/inward/record.url?scp=0242334157&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0242334157&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2003.09.102
DO - 10.1016/j.cplett.2003.09.102
M3 - Article
AN - SCOPUS:0242334157
SN - 0009-2614
VL - 381
SP - 30
EP - 36
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-2
ER -