The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states

Wilton L. Virgo; Timothy Steimle; Laura E. Aucoin; John M. Brown

doi:10.1016/j.cplett.2004.04.088

The permanent electric dipole moments of ruthenium monocarbide in the ³Π and ³Δ states

Wilton L. Virgo, Timothy Steimle, Laura E. Aucoin, John M. Brown

CLAS-NS: Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Stark shifts in the (0,0) bands of the [12.7] ³Π₂- [0.1] ³Δ₃ and [13.9] ³Π₁- [0.9] ³Δ₂ systems of ¹⁰²RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] ³Δ₃, [0.9] ³Δ ₃, [12.7] ³Π₂, and [13.9] ³Π₁ states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.

Original language	English (US)
Pages (from-to)	75-80
Number of pages	6
Journal	Chemical Physics Letters
Volume	391
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2004.04.088
State	Published - Jun 11 2004

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states",

abstract = "Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.",

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T1 - The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states

AU - Virgo, Wilton L.

AU - Steimle, Timothy

AU - Aucoin, Laura E.

AU - Brown, John M.

PY - 2004/6/11

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N2 - Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.

AB - Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.

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