The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states

Wilton L. Virgo, Timothy Steimle, Laura E. Aucoin, John M. Brown

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Abstract

Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.

Original languageEnglish (US)
Pages (from-to)75-80
Number of pages6
JournalChemical Physics Letters
Volume391
Issue number1-3
DOIs
StatePublished - Jun 11 2004

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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