Abstract
Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 75-80 |
| Number of pages | 6 |
| Journal | Chemical Physics Letters |
| Volume | 391 |
| Issue number | 1-3 |
| DOIs | |
| State | Published - Jun 11 2004 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states. / Virgo, Wilton L.; Steimle, Timothy; Aucoin, Laura E.; Brown, John M.
In: Chemical Physics Letters, Vol. 391, No. 1-3, 11.06.2004, p. 75-80.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states
AU - Virgo, Wilton L.
AU - Steimle, Timothy
AU - Aucoin, Laura E.
AU - Brown, John M.
PY - 2004/6/11
Y1 - 2004/6/11
N2 - Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.
AB - Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.
UR - http://www.scopus.com/inward/record.url?scp=2542434074&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=2542434074&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2004.04.088
DO - 10.1016/j.cplett.2004.04.088
M3 - Article
AN - SCOPUS:2542434074
VL - 391
SP - 75
EP - 80
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-3
ER -