TY - JOUR
T1 - The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states
AU - Virgo, Wilton L.
AU - Steimle, Timothy
AU - Aucoin, Laura E.
AU - Brown, John M.
N1 - Funding Information:
This work was supported by a grant from the Fundamental Interactions Branch, Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy (DF-FG03-95ER14518-A005).
PY - 2004/6/11
Y1 - 2004/6/11
N2 - Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.
AB - Stark shifts in the (0,0) bands of the [12.7] 3Π2- [0.1] 3Δ3 and [13.9] 3Π1- [0.9] 3Δ2 systems of 102RuC were analyzed to produce the magnitude of the permanent electric dipole moments, |μ|, for RuC in the [0.1] 3Δ3, [0.9] 3Δ 3, [12.7] 3Π2, and [13.9] 3Π1 states of 1.95(2), 1.86(2), 3.58(3) and 3.44(3) D, respectively. A comparison is made with ab initio predictions for RuC, and with experimental results for isovalent FeC and with RuN.
UR - http://www.scopus.com/inward/record.url?scp=2542434074&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=2542434074&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2004.04.088
DO - 10.1016/j.cplett.2004.04.088
M3 - Article
AN - SCOPUS:2542434074
VL - 391
SP - 75
EP - 80
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-3
ER -