The permanent electric dipole moment of PtO, PtS, PtN, and PtC

Timothy Steimle; K. Y. Jung; B. Z. Li

doi:10.1063/1.469750

The permanent electric dipole moment of PtO, PtS, PtN, and PtC

Timothy Steimle, K. Y. Jung, B. Z. Li

Molecular Sciences, School of (SMS)

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Abstract

The permanent electric dipole moments of the ground, and the low-lying excited electronic states of platinum monocarbide, PtC, platinum monoxide, PtO, and platinum monosulfide, PtS, were measured using a molecular beam optical Stark spectroscopic scheme. The determined values were (in Debye): PtO(X ³Σ^-) 2.77(2); PtO(A¹Σ⁺) 1.15(4); PtS[X(Ω = 0)] 1.78(2); PtS[β(Ω = 0)] 0.54(6); PtC(X¹Σ⁺) 0.99(5); and PtC(A¹Π) 2.454(3). These results, along with the previous results for PtN(X ²Π_1/2) 1.977(9); PtN(d⁴Π_1/2) 1.05(9) [J. Chem. Phys. 102, 643 (1995)], are used as a basis for a discussion of the nature of the electronic states.

Original language	English (US)
Pages (from-to)	1767-1772
Number of pages	6
Journal	The Journal of chemical physics
Volume	103
Issue number	5
DOIs	https://doi.org/10.1063/1.469750
State	Published - 1995

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "The permanent electric dipole moment of PtO, PtS, PtN, and PtC",

abstract = "The permanent electric dipole moments of the ground, and the low-lying excited electronic states of platinum monocarbide, PtC, platinum monoxide, PtO, and platinum monosulfide, PtS, were measured using a molecular beam optical Stark spectroscopic scheme. The determined values were (in Debye): PtO(X 3Σ-) 2.77(2); PtO(A1Σ+) 1.15(4); PtS[X(Ω = 0)] 1.78(2); PtS[β(Ω = 0)] 0.54(6); PtC(X1Σ+) 0.99(5); and PtC(A1Π) 2.454(3). These results, along with the previous results for PtN(X 2Π1/2) 1.977(9); PtN(d4Π1/2) 1.05(9) [J. Chem. Phys. 102, 643 (1995)], are used as a basis for a discussion of the nature of the electronic states.",

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T1 - The permanent electric dipole moment of PtO, PtS, PtN, and PtC

AU - Steimle, Timothy

AU - Jung, K. Y.

AU - Li, B. Z.

PY - 1995

Y1 - 1995

N2 - The permanent electric dipole moments of the ground, and the low-lying excited electronic states of platinum monocarbide, PtC, platinum monoxide, PtO, and platinum monosulfide, PtS, were measured using a molecular beam optical Stark spectroscopic scheme. The determined values were (in Debye): PtO(X 3Σ-) 2.77(2); PtO(A1Σ+) 1.15(4); PtS[X(Ω = 0)] 1.78(2); PtS[β(Ω = 0)] 0.54(6); PtC(X1Σ+) 0.99(5); and PtC(A1Π) 2.454(3). These results, along with the previous results for PtN(X 2Π1/2) 1.977(9); PtN(d4Π1/2) 1.05(9) [J. Chem. Phys. 102, 643 (1995)], are used as a basis for a discussion of the nature of the electronic states.

AB - The permanent electric dipole moments of the ground, and the low-lying excited electronic states of platinum monocarbide, PtC, platinum monoxide, PtO, and platinum monosulfide, PtS, were measured using a molecular beam optical Stark spectroscopic scheme. The determined values were (in Debye): PtO(X 3Σ-) 2.77(2); PtO(A1Σ+) 1.15(4); PtS[X(Ω = 0)] 1.78(2); PtS[β(Ω = 0)] 0.54(6); PtC(X1Σ+) 0.99(5); and PtC(A1Π) 2.454(3). These results, along with the previous results for PtN(X 2Π1/2) 1.977(9); PtN(d4Π1/2) 1.05(9) [J. Chem. Phys. 102, 643 (1995)], are used as a basis for a discussion of the nature of the electronic states.

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JO - The Journal of chemical physics

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The permanent electric dipole moment of PtO, PtS, PtN, and PtC

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