TY - JOUR
T1 - The permanent electric dipole moment of nickel oxide, NiO
AU - Kokkin, Damian L.
AU - Dewberry, David
AU - Steimle, Timothy
N1 - Funding Information:
This research at Arizona State University has been supported by a Grant from the National Science Foundation, Division of Chemistry , CHE-1265885 . The authors thank Prof. Colin Linton (University of New Brunswick) for his comments.
PY - 2014/8/5
Y1 - 2014/8/5
N2 - The optical Stark effect in numerous low-J branch features in the Ω=0+ ← X3Σ0- band near 19 040 cm-1 of nickel oxide, NiO, has been recorded and analyzed. The permanent electric dipole moment, μ→el, for the X3Σ0-(v=0) and [19.04] Ω=0+ states were determined to be 4.43 ± 0.04 D and 1.85 ± 0.16 D, respectively. The measured dipole moments of NiO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the [19.04] Ω=0+ state.
AB - The optical Stark effect in numerous low-J branch features in the Ω=0+ ← X3Σ0- band near 19 040 cm-1 of nickel oxide, NiO, has been recorded and analyzed. The permanent electric dipole moment, μ→el, for the X3Σ0-(v=0) and [19.04] Ω=0+ states were determined to be 4.43 ± 0.04 D and 1.85 ± 0.16 D, respectively. The measured dipole moments of NiO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the [19.04] Ω=0+ state.
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U2 - 10.1016/j.cplett.2014.06.027
DO - 10.1016/j.cplett.2014.06.027
M3 - Article
AN - SCOPUS:84903616753
SN - 0009-2614
VL - 609
SP - 1
EP - 5
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -