The permanent electric dipole moment of chromium monoxide

Timothy Steimle, David F. Nachman, Jeffrey E. Shirley, Charles W. Bauschlicher, Stephen R. Langhoff

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

The permanent electric dipole moments for the X5Π and B 5Π states of gas-phase chromium monoxide, CrO, have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 ± 0.13 and 4.1 ± 1.8 D for the X 5Π and B5Π states, respectively. The theoretical values determined for the X5Π state, using multireference configuration interaction iterative-natural-orbital and finite-field calculations, are in excellent agreement with the experimental value.

Original languageEnglish (US)
Pages (from-to)2049-2053
Number of pages5
JournalThe Journal of chemical physics
Volume91
Issue number4
DOIs
StatePublished - 1989

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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