The permanent electric dipole moment of chromium monoxide

Timothy Steimle; David F. Nachman; Jeffrey E. Shirley; Charles W. Bauschlicher; Stephen R. Langhoff

doi:10.1063/1.457065

The permanent electric dipole moment of chromium monoxide

Timothy Steimle, David F. Nachman, Jeffrey E. Shirley, Charles W. Bauschlicher, Stephen R. Langhoff

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The permanent electric dipole moments for the X₅Π and B ⁵Π states of gas-phase chromium monoxide, CrO, have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 ± 0.13 and 4.1 ± 1.8 D for the X ⁵Π and B⁵Π states, respectively. The theoretical values determined for the X⁵Π state, using multireference configuration interaction iterative-natural-orbital and finite-field calculations, are in excellent agreement with the experimental value.

Original language	English (US)
Pages (from-to)	2049-2053
Number of pages	5
Journal	The Journal of chemical physics
Volume	91
Issue number	4
DOIs	https://doi.org/10.1063/1.457065
State	Published - 1989

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "The permanent electric dipole moment of chromium monoxide",

abstract = "The permanent electric dipole moments for the X5Π and B 5Π states of gas-phase chromium monoxide, CrO, have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 ± 0.13 and 4.1 ± 1.8 D for the X 5Π and B5Π states, respectively. The theoretical values determined for the X5Π state, using multireference configuration interaction iterative-natural-orbital and finite-field calculations, are in excellent agreement with the experimental value.",

author = "Timothy Steimle and Nachman, {David F.} and Shirley, {Jeffrey E.} and Bauschlicher, {Charles W.} and Langhoff, {Stephen R.}",

year = "1989",

doi = "10.1063/1.457065",

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pages = "2049--2053",

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T1 - The permanent electric dipole moment of chromium monoxide

AU - Steimle, Timothy

AU - Nachman, David F.

AU - Shirley, Jeffrey E.

AU - Bauschlicher, Charles W.

AU - Langhoff, Stephen R.

PY - 1989

Y1 - 1989

N2 - The permanent electric dipole moments for the X5Π and B 5Π states of gas-phase chromium monoxide, CrO, have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 ± 0.13 and 4.1 ± 1.8 D for the X 5Π and B5Π states, respectively. The theoretical values determined for the X5Π state, using multireference configuration interaction iterative-natural-orbital and finite-field calculations, are in excellent agreement with the experimental value.

AB - The permanent electric dipole moments for the X5Π and B 5Π states of gas-phase chromium monoxide, CrO, have been experimentally determined using the sub-Doppler optical technique of intermodulated fluorescence spectroscopy in conjunction with the Stark effect. The measured values are 3.88 ± 0.13 and 4.1 ± 1.8 D for the X 5Π and B5Π states, respectively. The theoretical values determined for the X5Π state, using multireference configuration interaction iterative-natural-orbital and finite-field calculations, are in excellent agreement with the experimental value.

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The permanent electric dipole moment of chromium monoxide

Abstract

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