The morphology and chemistry evolution of inclusions in Fe-Si-Al-O melts

Youjong Kwon, Juhan Choi, Seetharaman Sridhar

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

This study aims to elucidate the process of inclusion precipitation in Fe-Si and Fe-Si-Al melts. Deoxidation experiments were carried out in a vacuum induction furnace (VIF) at 1873 K (1600 °C). In the Si-deoxidation experiments, spherical SiO2 of 1∼2 μm diameter was dominant. When 3 wt pct Si and 300 ppm Al were added, such that Al2O 3 and mullite were thermodynamically stable, the resulting inclusions depended on the addition sequence. When aluminum was added before silicon, spherical aluminum oxides were dominant after the Al addition, but after the Si addition, the number and size of alumina decreased and Al-Si oxides and mullite appeared with increasing time. When silicon was added before aluminum, spherical SiO2 was dominant after the Si addition, but after the Al addition, spherical and polygonal alumina inclusions were dominant. When Al/Si was added simultaneously, polygonal alumina inclusions were dominant initially, but with time, Al-Si oxide and mullite inclusions increased in numbers. If the Al amount in the Al/Si addition was increased to 600 ppm, only alumina was found. This study shows how, under similar thermodynamic conditions, the transient evolution of inclusions in iron melts in the Si-Al-O system differ depending on the alloy addition sequence.

Original languageEnglish (US)
Pages (from-to)814-824
Number of pages11
JournalMetallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume42
Issue number4
DOIs
StatePublished - Aug 2011
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

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