The millimeter wave spectrum of silver monoxide, AgO

Timothy Steimle; M. Tanimoto; K. Namiki; S. Saito

doi:10.1063/1.476196

The millimeter wave spectrum of silver monoxide, AgO

Timothy Steimle, M. Tanimoto, K. Namiki, S. Saito

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The pure rotational spectra of ¹⁰⁷AgO and ¹⁰⁹AgO were recorded in the 117-380 GHz spectral region using a dc-sputtering absorption cell. The ¹⁰⁷Ag(I=1/2) and ¹⁰⁹Ag(I=1/2) magnetic hyperfine parameters are interpreted in terms of plausible electronic configuration contributions to the X ²Π_i state. It is shown that the determined unusual sign of the Λ-doubling and Fermi contact parameters implies that the X ²Π_i state is dominated by a three open shell configuration. A comparison with isovalent CuO is made.

Original language	English (US)
Pages (from-to)	7616-7622
Number of pages	7
Journal	Journal of Chemical Physics
Volume	108
Issue number	18
DOIs	https://doi.org/10.1063/1.476196
State	Published - May 8 1998

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "The millimeter wave spectrum of silver monoxide, AgO",

abstract = "The pure rotational spectra of 107AgO and 109AgO were recorded in the 117-380 GHz spectral region using a dc-sputtering absorption cell. The 107Ag(I=1/2) and 109Ag(I=1/2) magnetic hyperfine parameters are interpreted in terms of plausible electronic configuration contributions to the X 2Πi state. It is shown that the determined unusual sign of the Λ-doubling and Fermi contact parameters implies that the X 2Πi state is dominated by a three open shell configuration. A comparison with isovalent CuO is made.",

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AU - Steimle, Timothy

AU - Tanimoto, M.

AU - Namiki, K.

AU - Saito, S.

PY - 1998/5/8

Y1 - 1998/5/8

N2 - The pure rotational spectra of 107AgO and 109AgO were recorded in the 117-380 GHz spectral region using a dc-sputtering absorption cell. The 107Ag(I=1/2) and 109Ag(I=1/2) magnetic hyperfine parameters are interpreted in terms of plausible electronic configuration contributions to the X 2Πi state. It is shown that the determined unusual sign of the Λ-doubling and Fermi contact parameters implies that the X 2Πi state is dominated by a three open shell configuration. A comparison with isovalent CuO is made.

AB - The pure rotational spectra of 107AgO and 109AgO were recorded in the 117-380 GHz spectral region using a dc-sputtering absorption cell. The 107Ag(I=1/2) and 109Ag(I=1/2) magnetic hyperfine parameters are interpreted in terms of plausible electronic configuration contributions to the X 2Πi state. It is shown that the determined unusual sign of the Λ-doubling and Fermi contact parameters implies that the X 2Πi state is dominated by a three open shell configuration. A comparison with isovalent CuO is made.

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The millimeter wave spectrum of silver monoxide, AgO

Abstract

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