The millimeter wave spectrum of silver monoxide, AgO

Timothy Steimle, M. Tanimoto, K. Namiki, S. Saito

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The pure rotational spectra of 107AgO and 109AgO were recorded in the 117-380 GHz spectral region using a dc-sputtering absorption cell. The 107Ag(I=1/2) and 109Ag(I=1/2) magnetic hyperfine parameters are interpreted in terms of plausible electronic configuration contributions to the X 2Πi state. It is shown that the determined unusual sign of the Λ-doubling and Fermi contact parameters implies that the X 2Πi state is dominated by a three open shell configuration. A comparison with isovalent CuO is made.

Original languageEnglish (US)
Pages (from-to)7616-7622
Number of pages7
JournalJournal of Chemical Physics
Volume108
Issue number18
DOIs
StatePublished - May 8 1998

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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