The millimeter wave spectrum of copper monoxide: CuO

Timothy Steimle; K. Namiki; S. Saito

doi:10.1063/1.474278

The millimeter wave spectrum of copper monoxide: CuO

Timothy Steimle, K. Namiki, S. Saito

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The pure rotational spectrum of ⁶⁵CuO in its ground X ²Π_i state was recorded in the 198-384 GHz spectral region using a dc-sputtering absorption spectrometer. The determined ⁶⁵Cu(I=3/2) hyperfine parameters are a= 214.1(35), b_F= -483.6(94), c= 72.5(95), d= 134.5(34), and eQq₀= -16.9(54) MHz, where a three standard deviation error estimate is given in parentheses. A plausible molecular orbital description for the X ²Π_i state based upon the determined parameters is given.

Original language	English (US)
Pages (from-to)	6109-6113
Number of pages	5
Journal	Journal of Chemical Physics
Volume	107
Issue number	16
DOIs	https://doi.org/10.1063/1.474278
State	Published - Oct 22 1997

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "The millimeter wave spectrum of copper monoxide: CuO",

abstract = "The pure rotational spectrum of 65CuO in its ground X 2Πi state was recorded in the 198-384 GHz spectral region using a dc-sputtering absorption spectrometer. The determined 65Cu(I=3/2) hyperfine parameters are a= 214.1(35), bF= -483.6(94), c= 72.5(95), d= 134.5(34), and eQq0= -16.9(54) MHz, where a three standard deviation error estimate is given in parentheses. A plausible molecular orbital description for the X 2Πi state based upon the determined parameters is given.",

author = "Timothy Steimle and K. Namiki and S. Saito",

year = "1997",

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doi = "10.1063/1.474278",

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T2 - CuO

AU - Steimle, Timothy

AU - Namiki, K.

AU - Saito, S.

PY - 1997/10/22

Y1 - 1997/10/22

N2 - The pure rotational spectrum of 65CuO in its ground X 2Πi state was recorded in the 198-384 GHz spectral region using a dc-sputtering absorption spectrometer. The determined 65Cu(I=3/2) hyperfine parameters are a= 214.1(35), bF= -483.6(94), c= 72.5(95), d= 134.5(34), and eQq0= -16.9(54) MHz, where a three standard deviation error estimate is given in parentheses. A plausible molecular orbital description for the X 2Πi state based upon the determined parameters is given.

AB - The pure rotational spectrum of 65CuO in its ground X 2Πi state was recorded in the 198-384 GHz spectral region using a dc-sputtering absorption spectrometer. The determined 65Cu(I=3/2) hyperfine parameters are a= 214.1(35), bF= -483.6(94), c= 72.5(95), d= 134.5(34), and eQq0= -16.9(54) MHz, where a three standard deviation error estimate is given in parentheses. A plausible molecular orbital description for the X 2Πi state based upon the determined parameters is given.

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The millimeter wave spectrum of copper monoxide: CuO

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