The microwave spectrum of NiH

Timothy Steimle, David F. Nachman, Jeffrey E. Shirley, David A. Fletcher, John M. Brown

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17 Scopus citations

Abstract

Numerous microwave transitions between the A-doubling components of vibrational levels in the X2Δ3/2 (ν = 0) state of NiH in the gas phase have been measured using the technique of microwave-optical double resonance (MODR) spectroscopy. An effective experimental method for the simultaneous introduction of low-frequency microwave radiation and optical laser radiation into a flowing reaction chamber has been demonstrated. Some A-doubling and magnetic hyperfine parameters were obtained from a least squares fit of an effective hamiltonian model to the observed transition frequencies. The spectroscopic parameters are interpreted in terms of the proposed electronic wavefunc-tions and state distribution.

Original languageEnglish (US)
Pages (from-to)923-932
Number of pages10
JournalMolecular Physics
Volume69
Issue number5
DOIs
StatePublished - Apr 1990

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ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Cite this

Steimle, T., Nachman, D. F., Shirley, J. E., Fletcher, D. A., & Brown, J. M. (1990). The microwave spectrum of NiH. Molecular Physics, 69(5), 923-932. https://doi.org/10.1080/00268979000100691