The lambda-doubling spectrum of 13CH, studied by microwave optical double resonance

Timothy Steimle, David R. Woodward, John M. Brown

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.

Original languageEnglish (US)
Pages (from-to)1276-1282
Number of pages7
JournalThe Journal of Chemical Physics
Volume85
Issue number3
StatePublished - 1985

Fingerprint

Hamiltonians
Wave functions
Microwaves
microwaves
wave functions
methylidyne
electronics

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

The lambda-doubling spectrum of 13CH, studied by microwave optical double resonance. / Steimle, Timothy; Woodward, David R.; Brown, John M.

In: The Journal of Chemical Physics, Vol. 85, No. 3, 1985, p. 1276-1282.

Research output: Contribution to journalArticle

@article{a29024e8a0ac4c19b470953565d2de5e,
title = "The lambda-doubling spectrum of 13CH, studied by microwave optical double resonance",
abstract = "Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.",
author = "Timothy Steimle and Woodward, {David R.} and Brown, {John M.}",
year = "1985",
language = "English (US)",
volume = "85",
pages = "1276--1282",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics Publising LLC",
number = "3",

}

TY - JOUR

T1 - The lambda-doubling spectrum of 13CH, studied by microwave optical double resonance

AU - Steimle, Timothy

AU - Woodward, David R.

AU - Brown, John M.

PY - 1985

Y1 - 1985

N2 - Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.

AB - Lambda-doubling transitions in 13CH in its X 2Π state have been observed using the technique of microwave optical double resonance (MODR). The frequencies of hyperfine components of five separate lambda-doubling transitions have been measured and used to determine the lambda-doubling and hyperfine parameters in the molecular Hamiltonian. The 13C hyperfine parameters re discussed in terms of the electronic wave function for CH in the X 2Π state.

UR - http://www.scopus.com/inward/record.url?scp=36549101232&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=36549101232&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:36549101232

VL - 85

SP - 1276

EP - 1282

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 3

ER -