The kinetics of successive addition of methyloxirane or ethyloxirane to alkanethiols in the presence of basic catalysts

Jan Chlebicki, Zbigniew Cichacz

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Rate constants and activation parameters for the direct addition reaction of methyloxirane or ethyloxirane to alkyl‐2‐hydroxyalkyl sulfides or successive oxypropylene and oxybutylene adducts in the presence of basic catalysts were determined at 373–403 K. This reaction was found to be of the first order with respect to alkyloxirane, sulfide, and catalyst.

Original languageEnglish (US)
Pages (from-to)243-252
Number of pages10
JournalInternational Journal of Chemical Kinetics
Volume22
Issue number3
DOIs
StatePublished - Jan 1 1990
Externally publishedYes

Fingerprint

Sulfides
sulfides
catalysts
Addition reactions
Catalysts
Kinetics
kinetics
adducts
Rate constants
Chemical activation
activation
propylene oxide

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

The kinetics of successive addition of methyloxirane or ethyloxirane to alkanethiols in the presence of basic catalysts. / Chlebicki, Jan; Cichacz, Zbigniew.

In: International Journal of Chemical Kinetics, Vol. 22, No. 3, 01.01.1990, p. 243-252.

Research output: Contribution to journalArticle

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