The insoluble carbonaceous material of CM chondrites

A possible source of discrete organic compounds under hydrothermal conditions

Hikaru Yabuta, Lynda Williams, George D. Cody, Conel M O D Alexander, Sandra Pizzarello

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

We report on the molecular analyses of the water- and solvent-soluble organic compounds released from the insoluble organic material (IOM) of the Murray meteorite upon treatment with weight-equivalent amounts of water and under conditions of elevated temperature and pressure. A varied suite of compounds was identified by gas chromatography-mass spectrometry (GC-MS). C3-C17 alkyl dicarboxylic acids and N- and O-containing hydroaromatic and aromatic compounds were found in the water extracts. The solvent extracts contained N-, O-, and S-containing aromatic compounds, a large number of their isomers and homologs, and a series of polycyclic aromatic hydrocarbons (PAHs) of up to five rings, together with noncondensed aromatic species such as substituted benzenes, biphenyl, and terphenyls as well as their substituted homologs, and hydrated PAHs. Isotopic analyses showed that residue IOMs after hydrothermal treatment had lower deuterium and 15N content than the untreated material (ΔD = -833‰ and Δ15N = -24.1) but did not differ from it in 13C composition. The effect of the hydrothermolytic release was recorded in significant differences between the NMR spectra of untreated and residue IOM. A possible relation to common precursors for the dicarboxylic acids found in the IOM and bulk extracts is discussed.

Original languageEnglish (US)
Pages (from-to)37-48
Number of pages12
JournalMeteoritics and Planetary Science
Volume42
Issue number1
StatePublished - Jan 2007

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carbonaceous materials
chondrites
organic materials
organic compounds
chondrite
organic compound
aromatic compounds
dicarboxylic acids
polycyclic aromatic hydrocarbons
Murray meteorite
water
PAH
terphenyls
gas chromatography
deuterium
acid
mass spectroscopy
isomers
benzene
meteorite

ASJC Scopus subject areas

  • Geophysics

Cite this

The insoluble carbonaceous material of CM chondrites : A possible source of discrete organic compounds under hydrothermal conditions. / Yabuta, Hikaru; Williams, Lynda; Cody, George D.; Alexander, Conel M O D; Pizzarello, Sandra.

In: Meteoritics and Planetary Science, Vol. 42, No. 1, 01.2007, p. 37-48.

Research output: Contribution to journalArticle

Yabuta, Hikaru ; Williams, Lynda ; Cody, George D. ; Alexander, Conel M O D ; Pizzarello, Sandra. / The insoluble carbonaceous material of CM chondrites : A possible source of discrete organic compounds under hydrothermal conditions. In: Meteoritics and Planetary Science. 2007 ; Vol. 42, No. 1. pp. 37-48.
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