Temperature-dependent direct transition energy in Ge0.99Sn0.01 film grown on Si measured by photoreflectance spectroscopy

Hyun Jun Jo, Mo Geun So, Jong Su Kim, Mee Yi Ryu, Yung Kee Yeo, John Kouvetakis

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Optical properties of a p-Ge0.99Sn0.01 film grown on an n-Si substrate have been investigated as a function of temperature and excitation laser intensity using photoreflectance (PR) spectroscopy. The Ge0.99Sn0.01 film was grown by ultra-high vacuum chemical vapor deposition method. Room temperature PR spectrum shows a dominant signal assigned to a direct transition from the conduction Γ valley to valence band at around 0.73 eV. The transition to spin-orbit split-off band is also observed at around 1.0 eV. In addition, Franz-Keldysh oscillations (FKOs) due to the internal electric field are observed above the direct bandgap transition energy. The direct transition energy obtained by an analysis of FKO extremum was 0.728 eV at room temperature. The internal electric fields are reduced as the laser excitation intensity increases due to the photovoltage effect. The temperature dependence of direct transition energy was also investigated.

Original languageEnglish (US)
Pages (from-to)295-300
Number of pages6
JournalThin Solid Films
Volume591
DOIs
StatePublished - Sep 30 2015

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Keywords

  • Franz-Keldysh oscillations
  • Germanium antimonide
  • Photoreflectance

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Metals and Alloys
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

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