Synthesis, structure and magnetic properties of a copper molybdate hybrid inorganic/organic solid with a novel 10-connected three-dimensional network topology

Matthew R. Montney; Justin G. Thomas; Ronald M. Supkowski; Ryan J. Trovitch; Jon Zubieta; Robert L. LaDuca

doi:10.1016/j.inoche.2009.04.017

Synthesis, structure and magnetic properties of a copper molybdate hybrid inorganic/organic solid with a novel 10-connected three-dimensional network topology

Matthew R. Montney, Justin G. Thomas, Ronald M. Supkowski, Ryan J. Trovitch, Jon Zubieta, Robert L. LaDuca

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Hydrothermal reaction of CuCl₂, MoO₃, and 4,4′-dipyridylketone (4,4′-dpk) afforded green crystals of the mixed metal oxide phase {[Cu₂(MoO₄)₂(4,4′-dpk)(H₂O)]·H₂O}_n (1). According to single-crystal X-ray diffraction, {Cu₂O₂} dimers link into 1-D {Cu₂O₂(μ-H₂O)}_n chains via bridging aqua ligands. These chains form [Cu₂(MoO₄)₂(H₂O)]_n slabs via linkage through tetrahedral molybdate anions. In turn, the copper molybdate slabs are pillared through tethering 4,4′-dpk ligands into a 10-connected three-dimensional lattice with an unprecedented 3¹²4³⁰5²6 topology. Variable temperature magnetic data above 140 K were fit to the Curie-Weiss law, with C = 0.17 cm³ K/mol Cu and Θ = 70 K, indicating likely ferromagnetic coupling within the dinuclear kernels of 1; low temperature data points towards the possibility of interdimer antiferromagnetic interactions.

Original language	English (US)
Pages (from-to)	534-539
Number of pages	6
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2009.04.017
State	Published - Jun 2009
Externally published	Yes

Keywords

Coordination polymer
Copper
Diimine
Ferromagnetism
Molybdate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2009.04.017

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Synthesis, structure and magnetic properties of a copper molybdate hybrid inorganic/organic solid with a novel 10-connected three-dimensional network topology. / Montney, Matthew R.; Thomas, Justin G.; Supkowski, Ronald M. et al.
In: Inorganic Chemistry Communications, Vol. 12, No. 6, 06.2009, p. 534-539.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis, structure and magnetic properties of a copper molybdate hybrid inorganic/organic solid with a novel 10-connected three-dimensional network topology",

abstract = "Hydrothermal reaction of CuCl2, MoO3, and 4,4′-dipyridylketone (4,4′-dpk) afforded green crystals of the mixed metal oxide phase {[Cu2(MoO4)2(4,4′-dpk)(H2O)]·H2O}n (1). According to single-crystal X-ray diffraction, {Cu2O2} dimers link into 1-D {Cu2O2(μ-H2O)}n chains via bridging aqua ligands. These chains form [Cu2(MoO4)2(H2O)]n slabs via linkage through tetrahedral molybdate anions. In turn, the copper molybdate slabs are pillared through tethering 4,4′-dpk ligands into a 10-connected three-dimensional lattice with an unprecedented 312430526 topology. Variable temperature magnetic data above 140 K were fit to the Curie-Weiss law, with C = 0.17 cm3 K/mol Cu and Θ = 70 K, indicating likely ferromagnetic coupling within the dinuclear kernels of 1; low temperature data points towards the possibility of interdimer antiferromagnetic interactions.",

keywords = "Coordination polymer, Copper, Diimine, Ferromagnetism, Molybdate",

author = "Montney, {Matthew R.} and Thomas, {Justin G.} and Supkowski, {Ronald M.} and Trovitch, {Ryan J.} and Jon Zubieta and LaDuca, {Robert L.}",

note = "Funding Information: We gratefully acknowledge Michigan State University and the American Chemical Society Petroleum Research Fund for funding this work. The crystallographic work at Syracuse University was funded by a grant from the National Science Foundation (CHE9987471). We thank Dr. Rui Huang for performing the elemental analysis. ",

year = "2009",

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doi = "10.1016/j.inoche.2009.04.017",

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T1 - Synthesis, structure and magnetic properties of a copper molybdate hybrid inorganic/organic solid with a novel 10-connected three-dimensional network topology

AU - Montney, Matthew R.

AU - Thomas, Justin G.

AU - Supkowski, Ronald M.

AU - Trovitch, Ryan J.

AU - Zubieta, Jon

AU - LaDuca, Robert L.

N1 - Funding Information: We gratefully acknowledge Michigan State University and the American Chemical Society Petroleum Research Fund for funding this work. The crystallographic work at Syracuse University was funded by a grant from the National Science Foundation (CHE9987471). We thank Dr. Rui Huang for performing the elemental analysis.

PY - 2009/6

Y1 - 2009/6

N2 - Hydrothermal reaction of CuCl2, MoO3, and 4,4′-dipyridylketone (4,4′-dpk) afforded green crystals of the mixed metal oxide phase {[Cu2(MoO4)2(4,4′-dpk)(H2O)]·H2O}n (1). According to single-crystal X-ray diffraction, {Cu2O2} dimers link into 1-D {Cu2O2(μ-H2O)}n chains via bridging aqua ligands. These chains form [Cu2(MoO4)2(H2O)]n slabs via linkage through tetrahedral molybdate anions. In turn, the copper molybdate slabs are pillared through tethering 4,4′-dpk ligands into a 10-connected three-dimensional lattice with an unprecedented 312430526 topology. Variable temperature magnetic data above 140 K were fit to the Curie-Weiss law, with C = 0.17 cm3 K/mol Cu and Θ = 70 K, indicating likely ferromagnetic coupling within the dinuclear kernels of 1; low temperature data points towards the possibility of interdimer antiferromagnetic interactions.

AB - Hydrothermal reaction of CuCl2, MoO3, and 4,4′-dipyridylketone (4,4′-dpk) afforded green crystals of the mixed metal oxide phase {[Cu2(MoO4)2(4,4′-dpk)(H2O)]·H2O}n (1). According to single-crystal X-ray diffraction, {Cu2O2} dimers link into 1-D {Cu2O2(μ-H2O)}n chains via bridging aqua ligands. These chains form [Cu2(MoO4)2(H2O)]n slabs via linkage through tetrahedral molybdate anions. In turn, the copper molybdate slabs are pillared through tethering 4,4′-dpk ligands into a 10-connected three-dimensional lattice with an unprecedented 312430526 topology. Variable temperature magnetic data above 140 K were fit to the Curie-Weiss law, with C = 0.17 cm3 K/mol Cu and Θ = 70 K, indicating likely ferromagnetic coupling within the dinuclear kernels of 1; low temperature data points towards the possibility of interdimer antiferromagnetic interactions.

KW - Coordination polymer

KW - Copper

KW - Diimine

KW - Ferromagnetism

KW - Molybdate

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Synthesis, structure and magnetic properties of a copper molybdate hybrid inorganic/organic solid with a novel 10-connected three-dimensional network topology

Abstract

Keywords

ASJC Scopus subject areas

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