TY - JOUR
T1 - Synthesis of high-pressure hydrous magnesium silicates
T2 - Observations and analysis
AU - Burnley, Pamela C.
AU - Navrotsky, Alexandra
PY - 1996
Y1 - 1996
N2 - Specimens of dense high-pressure hydrous magnesium silicates, notably phase A, phase B, and superhydrous phase B, have been synthesized for use in calorimetric and spectroscopic experiments. X-ray diffraction and electron microprobe analysis were used to study both major and minor phases occurring in the experimental products. We observed the formation of phase A at 16 GPa, 1172°C; phase B at 15 GPa, 1158°C; chondrodite at 12 GPa, 1158°C; and clinohumite at 12 GPa, 1170°C. These pressures and temperatures are higher than those reported in previous studies. We also observed the formation of phases E and superhydrous B at conditions at which they have been previously observed. However, we propose that there is a high-low transition in superhydrous B. We have not identified phase C in the pressure-temperature-bulk compositional space where it has been observed in previous studies. We conclude that this phase may be identical with superhydrous B, as previously suggested, or that in some studies a humite may have been misidentined as phase C.
AB - Specimens of dense high-pressure hydrous magnesium silicates, notably phase A, phase B, and superhydrous phase B, have been synthesized for use in calorimetric and spectroscopic experiments. X-ray diffraction and electron microprobe analysis were used to study both major and minor phases occurring in the experimental products. We observed the formation of phase A at 16 GPa, 1172°C; phase B at 15 GPa, 1158°C; chondrodite at 12 GPa, 1158°C; and clinohumite at 12 GPa, 1170°C. These pressures and temperatures are higher than those reported in previous studies. We also observed the formation of phases E and superhydrous B at conditions at which they have been previously observed. However, we propose that there is a high-low transition in superhydrous B. We have not identified phase C in the pressure-temperature-bulk compositional space where it has been observed in previous studies. We conclude that this phase may be identical with superhydrous B, as previously suggested, or that in some studies a humite may have been misidentined as phase C.
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U2 - 10.2138/am-1996-3-405
DO - 10.2138/am-1996-3-405
M3 - Article
AN - SCOPUS:0029751619
SN - 0003-004X
VL - 81
SP - 317
EP - 326
JO - American Mineralogist
JF - American Mineralogist
IS - 3-4
ER -