Synthesis of Cl2InN3, Br2InN3, and related adducts

Cory Steffek; Jeff McMurran; Brett Pleune; John Kouvetakis; Thomas E. Concolino; Arnold L. Rheingold

doi:10.1021/ic990387a

Synthesis of Cl₂InN₃, Br₂InN₃, and related adducts

Cory Steffek, Jeff McMurran, Brett Pleune, John Kouvetakis, Thomas E. Concolino, Arnold L. Rheingold

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The synthesis and properties of the new indium inorganic azides Cl₂InN₃ and Br₂InN₃ and corresponding adducts with common Lewis bases such as tetrahydrofuran (THF) and pyridine are presented. The solid-state molecular structure of the Cl₂InN₃(THF)₂ compound reveals a dinuclear [Cl₂InN₃(THF)₂]₂ complex which incorporates a cyclic In₂N₂ core formed by bridging azide ligands (see illustration).

Original language	English (US)
Pages (from-to)	1615-1617
Number of pages	3
Journal	Inorganic chemistry
Volume	39
Issue number	7
DOIs	https://doi.org/10.1021/ic990387a
State	Published - Apr 3 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic990387a

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abstract = "The synthesis and properties of the new indium inorganic azides Cl2InN3 and Br2InN3 and corresponding adducts with common Lewis bases such as tetrahydrofuran (THF) and pyridine are presented. The solid-state molecular structure of the Cl2InN3(THF)2 compound reveals a dinuclear [Cl2InN3(THF)2]2 complex which incorporates a cyclic In2N2 core formed by bridging azide ligands (see illustration).",

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year = "2000",

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doi = "10.1021/ic990387a",

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T1 - Synthesis of Cl2InN3, Br2InN3, and related adducts

AU - Steffek, Cory

AU - McMurran, Jeff

AU - Pleune, Brett

AU - Kouvetakis, John

AU - Concolino, Thomas E.

AU - Rheingold, Arnold L.

PY - 2000/4/3

Y1 - 2000/4/3

N2 - The synthesis and properties of the new indium inorganic azides Cl2InN3 and Br2InN3 and corresponding adducts with common Lewis bases such as tetrahydrofuran (THF) and pyridine are presented. The solid-state molecular structure of the Cl2InN3(THF)2 compound reveals a dinuclear [Cl2InN3(THF)2]2 complex which incorporates a cyclic In2N2 core formed by bridging azide ligands (see illustration).

AB - The synthesis and properties of the new indium inorganic azides Cl2InN3 and Br2InN3 and corresponding adducts with common Lewis bases such as tetrahydrofuran (THF) and pyridine are presented. The solid-state molecular structure of the Cl2InN3(THF)2 compound reveals a dinuclear [Cl2InN3(THF)2]2 complex which incorporates a cyclic In2N2 core formed by bridging azide ligands (see illustration).

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JO - Inorganic chemistry

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Synthesis of Cl₂InN₃, Br₂InN₃, and related adducts

Abstract

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CCDC 144398: Experimental Crystal Structure Determination

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Synthesis of Cl2InN3, Br2InN3, and related adducts

Abstract

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Datasets

CCDC 144398: Experimental Crystal Structure Determination

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Synthesis of Cl₂InN₃, Br₂InN₃, and related adducts