Synthesis of Cl2InN3, Br2InN3, and related adducts

Cory Steffek, Jeff McMurran, Brett Pleune, John Kouvetakis, Thomas E. Concolino, Arnold L. Rheingold

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

The synthesis and properties of the new indium inorganic azides Cl2InN3 and Br2InN3 and corresponding adducts with common Lewis bases such as tetrahydrofuran (THF) and pyridine are presented. The solid-state molecular structure of the Cl2InN3(THF)2 compound reveals a dinuclear [Cl2InN3(THF)2]2 complex which incorporates a cyclic In2N2 core formed by bridging azide ligands (see illustration).

Original languageEnglish (US)
Pages (from-to)1615-1617
Number of pages3
JournalInorganic chemistry
Volume39
Issue number7
DOIs
StatePublished - Apr 3 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Steffek, C., McMurran, J., Pleune, B., Kouvetakis, J., Concolino, T. E., & Rheingold, A. L. (2000). Synthesis of Cl2InN3, Br2InN3, and related adducts. Inorganic chemistry, 39(7), 1615-1617. https://doi.org/10.1021/ic990387a