Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture

Venkata S.Pavan K. Neti; Jun Wang; Shuguang Deng; Luis Echegoyen

doi:10.1155/2015/281616

Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO₂ Capture

Venkata S.Pavan K. Neti, Jun Wang, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride.The resultant amorphous polymer demonstrates a moderate surface area (S_BET = 428m² g^-1) and CO₂ adsorption ability (3.5wt%) and a CO₂/CH₄ selectivity of 5.6 at 273K/1 bar.

Original language	English (US)
Article number	281616
Journal	Journal of Chemistry
Volume	2015
DOIs	https://doi.org/10.1155/2015/281616
State	Published - 2015
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture",

abstract = "A new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride.The resultant amorphous polymer demonstrates a moderate surface area (SBET = 428m2 g-1) and CO2 adsorption ability (3.5wt%) and a CO2/CH4 selectivity of 5.6 at 273K/1 bar.",

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AU - Deng, Shuguang

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AB - A new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride.The resultant amorphous polymer demonstrates a moderate surface area (SBET = 428m2 g-1) and CO2 adsorption ability (3.5wt%) and a CO2/CH4 selectivity of 5.6 at 273K/1 bar.

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