Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework

Venkata S.Pavan K. Neti, Xiaofei Wu, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journalArticle

26 Scopus citations

Abstract

A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (SBET = 1315 m 2 g-1), and can store up to 0.8 wt% of H2 at 77 K and 1 bar and 0.6 wt% of CH4 at 298 K and 1 bar.

Original languageEnglish (US)
Pages (from-to)6892-6895
Number of pages4
JournalCrystEngComm
Volume15
Issue number35
DOIs
StatePublished - Sep 21 2013
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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