Synthesis of a benzothiazole nanoporous polymer for selective CO 2 adsorption

Venkata S Pavan K Neti, Xiaofei Wu, Ping Peng, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A new benzothiazole linked nanoporous polymer, imine benzothiazole polymer (IBTP), was synthesized via a Schiff base condensation reaction. IBTP showed high isosteric heat of adsorption (Qst) (37.8 kJ mol-1 at 273 K) and reasonable CO2 adsorption (7.8 wt% at 273 K/1 bar) as well as good selectivities, CO2/N2 (51) and CO 2/CH4 (6.3). The Brunauer-Emmett-Teller (BET) surface area of IBTP was 328 m2 g-1 and it also showed good thermal stability up to 450 °C under a N2 atmosphere, thus showing good potential for CO2 capture.

Original languageEnglish (US)
Pages (from-to)9669-9672
Number of pages4
JournalRSC Advances
Volume4
Issue number19
DOIs
StatePublished - 2014
Externally publishedYes

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Carbon Monoxide
Imines
Polymers
Adsorption
Condensation reactions
Schiff Bases
Thermodynamic stability
benzothiazole

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Synthesis of a benzothiazole nanoporous polymer for selective CO 2 adsorption. / Neti, Venkata S Pavan K; Wu, Xiaofei; Peng, Ping; Deng, Shuguang; Echegoyen, Luis.

In: RSC Advances, Vol. 4, No. 19, 2014, p. 9669-9672.

Research output: Contribution to journalArticle

Neti, Venkata S Pavan K ; Wu, Xiaofei ; Peng, Ping ; Deng, Shuguang ; Echegoyen, Luis. / Synthesis of a benzothiazole nanoporous polymer for selective CO 2 adsorption. In: RSC Advances. 2014 ; Vol. 4, No. 19. pp. 9669-9672.
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