Synthesis, characterization and adsorption properties of diethylenetriamine-modified hypercrosslinked resins for efficient removal of salicylic acid from aqueous solution

Jianhan Huang, Xiaoying Jin, Jinglin Mao, Bin Yuan, Rujie Deng, Shuguang Deng

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

We report an effective approach for tailoring the pore textural properties and surface polarity of a hypercrosslinked resin to enhance its adsorption capacity and selectivity for removing salicylic acid from aqueous solution. Four hypercrosslinked resins were synthesized by controlling the reaction time of the self Friedel-Crafts reaction of chloromethylated polystyrene-co-divinylbenzene, and then modified with diethylenetriamine to adjust their surface polarity. The resins were characterized with N 2 adsorption for pore textural properties, Fourier transform infrared spectroscopy (FT-IR) for surface functional groups, chemical analysis for residual chlorine content and weak basic exchange capacity. Adsorption equilibrium, kinetics and breakthrough performance were determined for the removal of salicylic acid from aqueous solution on a selected resin HJ-M01. The equilibrium adsorption capacity of salicylic acid on HJ-M01 is significantly higher than that on its precursor HJ-11 and a few commercial adsorbents including AB-8, XAD-4 and XAD-7. The dynamic adsorption capacity of salicylic acid on HJ-M01 was found to be 456.4mg/L at a feed concentration of 1000mg/L and 294K. The used resin could be fully regenerated with 1% sodium hydroxide solution. The hypercrosslinked resins being developed were promising alternatives to commercial adsorbents for removing salicylic acid and other volatile organic compounds (VOCs) from aqueous solution.

Original languageEnglish (US)
Pages (from-to)406-415
Number of pages10
JournalJournal of Hazardous Materials
Volume217-218
DOIs
StatePublished - May 30 2012
Externally publishedYes

Fingerprint

Salicylic acid
salicylic acid
Salicylic Acid
Adsorption
resin
aqueous solution
Resins
adsorption
divinyl benzene
Adsorbents
Volatile Organic Compounds
Sodium Hydroxide
Friedel-Crafts reaction
Surface Properties
Chlorine
Polystyrenes
Fourier Transform Infrared Spectroscopy
Volatile organic compounds
FTIR spectroscopy
chemical analysis

Keywords

  • Adsorption
  • Breakthrough
  • Equilibrium
  • Hypercrosslinked resins
  • Kinetics
  • Salicylic acid

ASJC Scopus subject areas

  • Health, Toxicology and Mutagenesis
  • Pollution
  • Waste Management and Disposal
  • Environmental Chemistry
  • Environmental Engineering

Cite this

Synthesis, characterization and adsorption properties of diethylenetriamine-modified hypercrosslinked resins for efficient removal of salicylic acid from aqueous solution. / Huang, Jianhan; Jin, Xiaoying; Mao, Jinglin; Yuan, Bin; Deng, Rujie; Deng, Shuguang.

In: Journal of Hazardous Materials, Vol. 217-218, 30.05.2012, p. 406-415.

Research output: Contribution to journalArticle

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AB - We report an effective approach for tailoring the pore textural properties and surface polarity of a hypercrosslinked resin to enhance its adsorption capacity and selectivity for removing salicylic acid from aqueous solution. Four hypercrosslinked resins were synthesized by controlling the reaction time of the self Friedel-Crafts reaction of chloromethylated polystyrene-co-divinylbenzene, and then modified with diethylenetriamine to adjust their surface polarity. The resins were characterized with N 2 adsorption for pore textural properties, Fourier transform infrared spectroscopy (FT-IR) for surface functional groups, chemical analysis for residual chlorine content and weak basic exchange capacity. Adsorption equilibrium, kinetics and breakthrough performance were determined for the removal of salicylic acid from aqueous solution on a selected resin HJ-M01. The equilibrium adsorption capacity of salicylic acid on HJ-M01 is significantly higher than that on its precursor HJ-11 and a few commercial adsorbents including AB-8, XAD-4 and XAD-7. The dynamic adsorption capacity of salicylic acid on HJ-M01 was found to be 456.4mg/L at a feed concentration of 1000mg/L and 294K. The used resin could be fully regenerated with 1% sodium hydroxide solution. The hypercrosslinked resins being developed were promising alternatives to commercial adsorbents for removing salicylic acid and other volatile organic compounds (VOCs) from aqueous solution.

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