Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes

K. Xu; Charles Angell

doi:10.1016/0013-4686(95)00203-Q

Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes

K. Xu, Charles Angell

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A series of lithium sulfonates intended for battery purpose are synthesized by means of Strecker synthesis or sulfinatodehalogenation-oxidation: LiO₃SRSO₃Li; R = alkylene (I) or oligo-oxyethylene (II): RSO₃Li; R = perfluoroalkyls (III) or perhaloalkyls (IV). Thermal, electrical and electrochemical properties of these and their molten salt mixtures with other components are evaluated as lithium ion conducting electrolytes. The best recipe containing a newly synthesized lithium sulfonate gives a room temperature conductivity of 10^-2.8S cm^-1 with a 4.0 V electrochemical domain.

Original language	English (US)
Pages (from-to)	2401-2403
Number of pages	3
Journal	Electrochimica Acta
Volume	40
Issue number	13-14
DOIs	https://doi.org/10.1016/0013-4686(95)00203-Q
State	Published - Oct 1995

Keywords

electrolytes
lithium battery
molten salt

ASJC Scopus subject areas

Chemical Engineering(all)
Electrochemistry

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10.1016/0013-4686(95)00203-Q

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title = "Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes",

abstract = "A series of lithium sulfonates intended for battery purpose are synthesized by means of Strecker synthesis or sulfinatodehalogenation-oxidation: LiO3SRSO3Li; R = alkylene (I) or oligo-oxyethylene (II): RSO3Li; R = perfluoroalkyls (III) or perhaloalkyls (IV). Thermal, electrical and electrochemical properties of these and their molten salt mixtures with other components are evaluated as lithium ion conducting electrolytes. The best recipe containing a newly synthesized lithium sulfonate gives a room temperature conductivity of 10-2.8S cm-1 with a 4.0 V electrochemical domain.",

keywords = "electrolytes, lithium battery, molten salt",

author = "K. Xu and Charles Angell",

note = "Funding Information: Acknowledgement-This work was supported by DOE underG rant No. DEFG02-89ER4535398",

year = "1995",

month = oct,

doi = "10.1016/0013-4686(95)00203-Q",

language = "English (US)",

volume = "40",

pages = "2401--2403",

journal = "Electrochimica Acta",

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TY - JOUR

T1 - Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes

AU - Xu, K.

AU - Angell, Charles

N1 - Funding Information: Acknowledgement-This work was supported by DOE underG rant No. DEFG02-89ER4535398

PY - 1995/10

Y1 - 1995/10

N2 - A series of lithium sulfonates intended for battery purpose are synthesized by means of Strecker synthesis or sulfinatodehalogenation-oxidation: LiO3SRSO3Li; R = alkylene (I) or oligo-oxyethylene (II): RSO3Li; R = perfluoroalkyls (III) or perhaloalkyls (IV). Thermal, electrical and electrochemical properties of these and their molten salt mixtures with other components are evaluated as lithium ion conducting electrolytes. The best recipe containing a newly synthesized lithium sulfonate gives a room temperature conductivity of 10-2.8S cm-1 with a 4.0 V electrochemical domain.

AB - A series of lithium sulfonates intended for battery purpose are synthesized by means of Strecker synthesis or sulfinatodehalogenation-oxidation: LiO3SRSO3Li; R = alkylene (I) or oligo-oxyethylene (II): RSO3Li; R = perfluoroalkyls (III) or perhaloalkyls (IV). Thermal, electrical and electrochemical properties of these and their molten salt mixtures with other components are evaluated as lithium ion conducting electrolytes. The best recipe containing a newly synthesized lithium sulfonate gives a room temperature conductivity of 10-2.8S cm-1 with a 4.0 V electrochemical domain.

KW - electrolytes

KW - lithium battery

KW - molten salt

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U2 - 10.1016/0013-4686(95)00203-Q

DO - 10.1016/0013-4686(95)00203-Q

M3 - Article

AN - SCOPUS:0000712894

SN - 0013-4686

VL - 40

SP - 2401

EP - 2403

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 13-14

ER -

Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes

Abstract

Keywords

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