Synthesis and characterization of large colloidal cobalt particles

Verónica Salgueiriño-Maceira, Miguel A. Correa-Duarte, Michael Farle, M. Arturo López-Quintela, Karl Sieradzki, Rodolfo Diaz

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48 Scopus citations

Abstract

Large colloidal environmentally stable silica-coated cobalt particles were synthesized by combining the sodium borohydride reduction in aqueous solution and the Stöber method. Low size polydisperse cobalt spheres with an average size of 95 nm were synthesized by using a borohydride reduction method and were subsequently coated with a thin layer of silica by means of hydrolysis and condensation of tetraethylorothosilicate (TEOS) in an aqueous/ ethanolic solution. The large uniform cobalt spheres consist of smaller metallic Co clusters, explaining the superparamagnetic behavior of the spheres. The particles were investigated by transmission electron microscopy (TEM) and vibrating sample magnetometry (VSM).

Original languageEnglish (US)
Pages (from-to)1455-1458
Number of pages4
JournalLangmuir
Volume22
Issue number4
DOIs
StatePublished - Feb 14 2006

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ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Salgueiriño-Maceira, V., Correa-Duarte, M. A., Farle, M., López-Quintela, M. A., Sieradzki, K., & Diaz, R. (2006). Synthesis and characterization of large colloidal cobalt particles. Langmuir, 22(4), 1455-1458. https://doi.org/10.1021/la0526885