Surface tension and molar surface free energy and entropy of water to -27.2 °C

M. A. Floriano, Charles Angell

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

To remove a deficiency in the growing data base on supercooled water, the surface tension of water has been measured, using a small-sample capillary rise method, down to -27.2 °C. The data do not accord with extrapolations of equations best fitting data above 0 °C but show a more rapid increase with decreasing temperature. This distinguishes water from other hydrogen-bonded fluids and focuses attention on weaknesses of classical interpretations of the temperature dependence of the surface tension. The observations are related to recent molecular dynamics studies of water surface tension. The possibility of an artifact in experimental studies, caused by anomalous gas solubility in the supercooled regime, is recognized.

Original languageEnglish (US)
Pages (from-to)4199-4202
Number of pages4
JournalJournal of Physical Chemistry®
Volume94
Issue number10
StatePublished - 1990

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Free energy
Surface tension
interfacial tension
Entropy
free energy
entropy
Water
water
data bases
Extrapolation
Molecular dynamics
artifacts
extrapolation
Hydrogen
solubility
Solubility
Gases
molecular dynamics
Temperature
temperature dependence

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Surface tension and molar surface free energy and entropy of water to -27.2 °C. / Floriano, M. A.; Angell, Charles.

In: Journal of Physical Chemistry®, Vol. 94, No. 10, 1990, p. 4199-4202.

Research output: Contribution to journalArticle

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