Sulfur doped nanocrystalline diamond films as field enhancement based thermionic emitters and their role in energy conversion

F. A.M. Koeck, R. J. Nemanich

Research output: Contribution to journalConference articlepeer-review

22 Scopus citations

Abstract

Sulfur doped nanocrystalline diamond films, like other nanostructured carbon films, exhibit electron emission characterized by a spatial non-uniformity of the field enhancement factor. While field emission effects are observed at room temperature, an increase in emitter temperature is accompanied by an amplified emission current with a simultaneous drop in the threshold field. At low extraction fields a fit of the emission current to the Richardson equation indicates a material work function of ∼2.5 eV. The Schottky formula describes thermionic emission at a moderate field and is utilized to determine the work function at an electric field of 0.8 V/μm with a value of ∼1.7 eV and a concurrently reduced Richardson constant. This significant difference in the work function of 2.5 and 1.7 eV for 0.5 and 0.8V/μm, respectively can be attributed to field enhancement effects.

Original languageEnglish (US)
Pages (from-to)2051-2054
Number of pages4
JournalDiamond and Related Materials
Volume14
Issue number11-12
DOIs
StatePublished - Nov 2005
Externally publishedYes
EventProceedings of the 10th International Conference on New Diamond Science and Technology (ICNDST-10) ICNDST-10 Special Issue -
Duration: May 11 2005May 14 2005

Keywords

  • CVD
  • Doped nanocrystalline diamond
  • Energy conversion
  • Field emission
  • Thermionic emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • General Chemistry
  • Mechanical Engineering
  • Materials Chemistry
  • Electrical and Electronic Engineering

Fingerprint

Dive into the research topics of 'Sulfur doped nanocrystalline diamond films as field enhancement based thermionic emitters and their role in energy conversion'. Together they form a unique fingerprint.

Cite this