Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Keren Zhang; Kevin J. Drummey; Nicholas G. Moon; William D. Chiang; Timothy E. Long

doi:10.1039/c6py00426a

Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Keren Zhang, Kevin J. Drummey, Nicholas G. Moon, William D. Chiang, Timothy E. Long

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

Original language	English (US)
Pages (from-to)	3370-3374
Number of pages	5
Journal	Polymer Chemistry
Volume	7
Issue number	20
DOIs	https://doi.org/10.1039/c6py00426a
State	Published - May 28 2016
Externally published	Yes

ASJC Scopus subject areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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10.1039/c6py00426a

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title = "Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers",

abstract = "A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.",

author = "Keren Zhang and Drummey, {Kevin J.} and Moon, {Nicholas G.} and Chiang, {William D.} and Long, {Timothy E.}",

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doi = "10.1039/c6py00426a",

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AU - Zhang, Keren

AU - Drummey, Kevin J.

AU - Moon, Nicholas G.

AU - Chiang, William D.

AU - Long, Timothy E.

PY - 2016/5/28

Y1 - 2016/5/28

N2 - A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

AB - A facile, two-step synthesis afforded styrenic DABCO salt monomers bearing two cyclic quaternary ammonium cations. Free radical polymerization of the DABCO salt monomers yielded homopolymers and copolymers with n-butyl acrylate. DABCO salt-containing ionomers exhibited superior thermomechanical properties with extended plateau regimes compared to ionomers bearing singly-charged pendant groups.

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Styrenic DABCO salt-containing monomers for the synthesis of novel charged polymers

Abstract

ASJC Scopus subject areas

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