Studies on the reaction and quantum chemistry of thiazolidine-2-thione and (R)-thiazolidine-2-thione-4-carboxylic ethyl ester with α-bromopropylchloride

Ye Zhi Li, Chun Xiao Guo, Yan Qing Tian, Xiao Gang Zhao, Hua Min Huang

    Research output: Contribution to journalArticlepeer-review

    1 Scopus citations

    Abstract

    Thiazolidine-2-α-bromopropyonyl thiol ester 2a and optically active (R)-thiazolidine-4-ethoxy carbonyl-2-α-bromopropyonyl thiol ester 2b were perpared by the reaction of α-bromopropyonyl chloride with thiazolidine-2-thione and (R)-thiazolidine-2-thione-4-carboxylic ethyl ester. The electronic structures of products and reactants were studied by molecular orbital PM3 method. The reaction enthalpies of products and the transition state of reactant 1a were obtained.

    Original languageEnglish (US)
    Pages (from-to)x28-958
    JournalKao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
    Volume19
    Issue number6
    StatePublished - Dec 1 1998

    Keywords

    • (r)-thiazolidine-2-thione-4-carboxylic ethyl ester
    • (r)-thiazolidine-4-ethoxycarbonyl-2-α-bromopropyonyl thiol ester
    • Electronic structure
    • Reaction enthalpies
    • Thiazolidine-2-α-bromopropyonyl thiol ester

    ASJC Scopus subject areas

    • Chemistry(all)

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