Structural and optical properties of PbTiO3 grown on SrTiO 3 substrates by peroxide MBE

Natalia Izyumskaya; Vitaliy Avrutin; Xing Gu; Umit Ozgur; Tae Dong Kang; Hosun Lee; David Smith; Hadis Morkoc

doi:10.1557/proc-0966-t07-04

Structural and optical properties of PbTiO₃ grown on SrTiO ₃ substrates by peroxide MBE

Natalia Izyumskaya, Vitaliy Avrutin, Xing Gu, Umit Ozgur, Tae Dong Kang, Hosun Lee, David Smith, Hadis Morkoc

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

3 Scopus citations

Abstract

Single-crystal PbTiO₃ layers were grown on (001) SrTiO ₃ substrates by molecular beam epitaxy using hydrogen peroxide as an oxidant. Phase composition and structural properties of the films were examined as a function of growth parameters. It was found that single-phase PbTiO ₃ films grew epitaxially at substrate temperatures of 600°C and higher, whereas layers grown at lower temperature contained PbO inclusions. The epitaxial relationship between the films and the substrates was (001)PbTiO ₃//(001 )SrTiO₃ and PbTiO₃[100]//SrTiO ₃[100]. No evidence of a-domains was found. Full widths at half maximum of (001) PbTiO₃ rocking curves were as low as 6-8 arcmin for 50-60 nm thick films, indicating high crystal quality of the films. From ellipsometric measurements, refractive index and band gap of PbTiO₃ were found to be 2.66 at 633 nm and 3.8 eV, respectively.

Original language	English (US)
Title of host publication	Ferroelectrics and Multiferroics
Publisher	Materials Research Society
Pages	217-222
Number of pages	6
ISBN (Print)	9781604234183
DOIs	https://doi.org/10.1557/proc-0966-t07-04
State	Published - 2006
Event	2006 MRS Fall Meeting - Boston, MA, United States Duration: Nov 27 2006 → Dec 1 2006

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	966
ISSN (Print)	0272-9172

Other

Other	2006 MRS Fall Meeting
Country/Territory	United States
City	Boston, MA
Period	11/27/06 → 12/1/06

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1557/proc-0966-t07-04

Cite this

Izyumskaya, N., Avrutin, V., Gu, X., Ozgur, U., Kang, T. D., Lee, H., Smith, D., & Morkoc, H. (2006). Structural and optical properties of PbTiO₃ grown on SrTiO ₃ substrates by peroxide MBE. In Ferroelectrics and Multiferroics (pp. 217-222). (Materials Research Society Symposium Proceedings; Vol. 966). Materials Research Society. https://doi.org/10.1557/proc-0966-t07-04

Structural and optical properties of PbTiO₃ grown on SrTiO ₃ substrates by peroxide MBE. / Izyumskaya, Natalia; Avrutin, Vitaliy; Gu, Xing et al.
Ferroelectrics and Multiferroics. Materials Research Society, 2006. p. 217-222 (Materials Research Society Symposium Proceedings; Vol. 966).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Izyumskaya, N, Avrutin, V, Gu, X, Ozgur, U, Kang, TD, Lee, H, Smith, D & Morkoc, H 2006, Structural and optical properties of PbTiO₃ grown on SrTiO ₃ substrates by peroxide MBE. in Ferroelectrics and Multiferroics. Materials Research Society Symposium Proceedings, vol. 966, Materials Research Society, pp. 217-222, 2006 MRS Fall Meeting, Boston, MA, United States, 11/27/06. https://doi.org/10.1557/proc-0966-t07-04

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abstract = "Single-crystal PbTiO3 layers were grown on (001) SrTiO 3 substrates by molecular beam epitaxy using hydrogen peroxide as an oxidant. Phase composition and structural properties of the films were examined as a function of growth parameters. It was found that single-phase PbTiO 3 films grew epitaxially at substrate temperatures of 600°C and higher, whereas layers grown at lower temperature contained PbO inclusions. The epitaxial relationship between the films and the substrates was (001)PbTiO 3//(001 )SrTiO3 and PbTiO3[100]//SrTiO 3[100]. No evidence of a-domains was found. Full widths at half maximum of (001) PbTiO3 rocking curves were as low as 6-8 arcmin for 50-60 nm thick films, indicating high crystal quality of the films. From ellipsometric measurements, refractive index and band gap of PbTiO3 were found to be 2.66 at 633 nm and 3.8 eV, respectively.",

author = "Natalia Izyumskaya and Vitaliy Avrutin and Xing Gu and Umit Ozgur and Kang, {Tae Dong} and Hosun Lee and David Smith and Hadis Morkoc",

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AU - Izyumskaya, Natalia

AU - Avrutin, Vitaliy

AU - Gu, Xing

AU - Ozgur, Umit

AU - Kang, Tae Dong

AU - Lee, Hosun

AU - Smith, David

AU - Morkoc, Hadis

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N2 - Single-crystal PbTiO3 layers were grown on (001) SrTiO 3 substrates by molecular beam epitaxy using hydrogen peroxide as an oxidant. Phase composition and structural properties of the films were examined as a function of growth parameters. It was found that single-phase PbTiO 3 films grew epitaxially at substrate temperatures of 600°C and higher, whereas layers grown at lower temperature contained PbO inclusions. The epitaxial relationship between the films and the substrates was (001)PbTiO 3//(001 )SrTiO3 and PbTiO3[100]//SrTiO 3[100]. No evidence of a-domains was found. Full widths at half maximum of (001) PbTiO3 rocking curves were as low as 6-8 arcmin for 50-60 nm thick films, indicating high crystal quality of the films. From ellipsometric measurements, refractive index and band gap of PbTiO3 were found to be 2.66 at 633 nm and 3.8 eV, respectively.

AB - Single-crystal PbTiO3 layers were grown on (001) SrTiO 3 substrates by molecular beam epitaxy using hydrogen peroxide as an oxidant. Phase composition and structural properties of the films were examined as a function of growth parameters. It was found that single-phase PbTiO 3 films grew epitaxially at substrate temperatures of 600°C and higher, whereas layers grown at lower temperature contained PbO inclusions. The epitaxial relationship between the films and the substrates was (001)PbTiO 3//(001 )SrTiO3 and PbTiO3[100]//SrTiO 3[100]. No evidence of a-domains was found. Full widths at half maximum of (001) PbTiO3 rocking curves were as low as 6-8 arcmin for 50-60 nm thick films, indicating high crystal quality of the films. From ellipsometric measurements, refractive index and band gap of PbTiO3 were found to be 2.66 at 633 nm and 3.8 eV, respectively.

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