Strong binding site molarity of MOFs and its effect on CO<inf>2</inf> adsorption

Yang Liu, Jing Liu, Jerry Lin

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Metal organic frameworks (MOFs) with strong binding sites usually have remarkable CO<inf>2</inf> adsorption capacity at ambient conditions. A new material parameter, the strong binding site molarity, defined as the number of the strong binding sites divided by the molecular weight of the unit cell of MOF, is introduced to understand CO<inf>2</inf> adsorption on these MOFs. The CO<inf>2</inf> adsorption capacity can be correlated to the strong binding site molarity in 1:1 ratio. The strong binding site coverage by CO<inf>2</inf> molecules can also be correlated to the isosteric heat of CO<inf>2</inf> adsorption at a given pressure. The strong binding site molarity is used to predict CO<inf>2</inf> adsorption amount of several new types of MOFs to show its uses in selection or design of MOFs for CO<inf>2</inf> capture.

Original languageEnglish (US)
Article number7108
Pages (from-to)242-245
Number of pages4
JournalMicroporous and Mesoporous Materials
Volume214
DOIs
StatePublished - Sep 15 2015

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Keywords

  • CO<inf>2</inf> adsorption
  • MOFs
  • Site coverage
  • Strong binding sites molarity

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Strong binding site molarity of MOFs and its effect on CO<inf>2</inf> adsorption. / Liu, Yang; Liu, Jing; Lin, Jerry.

In: Microporous and Mesoporous Materials, Vol. 214, 7108, 15.09.2015, p. 242-245.

Research output: Contribution to journalArticle

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