Steroids and Related Natural Products. 88. Synthesis of Periplogenin

Yoshiaki Kamano, George Pettit, M. Tozawa

Research output: Contribution to journalLetter

7 Scopus citations

Abstract

Digitoxigenin (3a) was converted to canarigenin (6), periplogenin (1c), and uzarigenin (3b); the use of tert-butyl hypochlorite for oxidation of digitoxigenin (3a) to chloro ketone 4 and application of chromium(II) acetate for reduction of epoxy ketone 7 to hydroxy ketone 8 represented particularly convenient aspects of these synthetic transformations.

Original languageEnglish (US)
Pages (from-to)2319-2320
Number of pages2
JournalJournal of Organic Chemistry
Volume39
Issue number15
DOIs
StatePublished - Jul 1 1974

ASJC Scopus subject areas

  • Organic Chemistry

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