TY - JOUR
T1 - Steric effects on nascent vibrational distributions of the HCN product produced in CN radical reactions with ethane, propane and chloroform
AU - Morris, Vernon R.
AU - Mohammad, Fida
AU - Valdry, Lynnette
AU - Jackson, William M.
PY - 1994/8/8
Y1 - 1994/8/8
N2 - Time-resolved IR emission spectroscopy (TRIES) has been used to study infrared emission in the 3400-3100 cm-1 region from HCN molecules produced when CN radicals abstract a hydrogen atom from ethane, propane, and chloroform. From these observations the nascent vibrational distributions of the HCN produced were derived. The nascent vibrational population distributions of the product HCN in all of the reactions are non-statistical and inverted in both the pure CH stretch (00p) and CH stretch-bend (0np) series.
AB - Time-resolved IR emission spectroscopy (TRIES) has been used to study infrared emission in the 3400-3100 cm-1 region from HCN molecules produced when CN radicals abstract a hydrogen atom from ethane, propane, and chloroform. From these observations the nascent vibrational distributions of the HCN produced were derived. The nascent vibrational population distributions of the product HCN in all of the reactions are non-statistical and inverted in both the pure CH stretch (00p) and CH stretch-bend (0np) series.
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U2 - 10.1016/0009-2614(94)00212-6
DO - 10.1016/0009-2614(94)00212-6
M3 - Article
AN - SCOPUS:0000468450
SN - 0009-2614
VL - 220
SP - 448
EP - 454
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 6
ER -