Stationary points in the temperature dependence of electron transfer rates

Dmitry V. Matyushov; Roland Schmid

doi:10.1016/0009-2614(94)00193-6

Stationary points in the temperature dependence of electron transfer rates

Dmitry V. Matyushov, Roland Schmid

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Abstract

The temperature dependence of the rate of electron transfer is analyzed in the framework of a molecular theory presented recently, characterized by decoupling the total solvent reorganization energy into two contributions featuring reorganizations of permanent dipoles as well as solvent density. The inclusion of the temperature dependence of liquid density reorganization can give rise to a maximum in the Arrhenius coordinates for electron transfer in the inverted region and for exothermic reactions with small activation barriers as well.

Original language	English (US)
Pages (from-to)	359-364
Number of pages	6
Journal	Chemical Physics Letters
Volume	220
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(94)00193-6
State	Published - Aug 8 1994
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(94)00193-6

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title = "Stationary points in the temperature dependence of electron transfer rates",

abstract = "The temperature dependence of the rate of electron transfer is analyzed in the framework of a molecular theory presented recently, characterized by decoupling the total solvent reorganization energy into two contributions featuring reorganizations of permanent dipoles as well as solvent density. The inclusion of the temperature dependence of liquid density reorganization can give rise to a maximum in the Arrhenius coordinates for electron transfer in the inverted region and for exothermic reactions with small activation barriers as well.",

author = "Matyushov, {Dmitry V.} and Roland Schmid",

year = "1994",

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doi = "10.1016/0009-2614(94)00193-6",

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T1 - Stationary points in the temperature dependence of electron transfer rates

AU - Matyushov, Dmitry V.

AU - Schmid, Roland

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N2 - The temperature dependence of the rate of electron transfer is analyzed in the framework of a molecular theory presented recently, characterized by decoupling the total solvent reorganization energy into two contributions featuring reorganizations of permanent dipoles as well as solvent density. The inclusion of the temperature dependence of liquid density reorganization can give rise to a maximum in the Arrhenius coordinates for electron transfer in the inverted region and for exothermic reactions with small activation barriers as well.

AB - The temperature dependence of the rate of electron transfer is analyzed in the framework of a molecular theory presented recently, characterized by decoupling the total solvent reorganization energy into two contributions featuring reorganizations of permanent dipoles as well as solvent density. The inclusion of the temperature dependence of liquid density reorganization can give rise to a maximum in the Arrhenius coordinates for electron transfer in the inverted region and for exothermic reactions with small activation barriers as well.

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U2 - 10.1016/0009-2614(94)00193-6

DO - 10.1016/0009-2614(94)00193-6

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VL - 220

SP - 359

EP - 364

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Stationary points in the temperature dependence of electron transfer rates

Abstract

ASJC Scopus subject areas

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