TY - JOUR
T1 - Solvation dynamics in the plastic crystal and supercooled liquid state of ethanol
AU - Richert, Ranko
PY - 2003/8/20
Y1 - 2003/8/20
N2 - The dynamics of ethanol in its plastic crystalline and supercooled liquid state has been measured using triplet state solvation dynamics techniques. This study focuses on temperatures near the respective glass transitions Tg of the two distinct phases, where the structural relaxation times are between 1 ms and 10 s. In the plastic crystal, the correlation times of the Stokes shift dynamics match the longitudinal time constants of the system as derived from dielectric relaxation data. Additionally, a maximum of the time resolved optical linewidths is indicative of heterogeneous dynamics in the plastic crystal. The supercooled liquid state is obtained after quenching the liquid from room temperature to below Tg and displays relaxation times that are a factor of 100 faster compared with the plastic crystal at the same temperature. The results do not reveal different translational contributions to solvation for the two phases.
AB - The dynamics of ethanol in its plastic crystalline and supercooled liquid state has been measured using triplet state solvation dynamics techniques. This study focuses on temperatures near the respective glass transitions Tg of the two distinct phases, where the structural relaxation times are between 1 ms and 10 s. In the plastic crystal, the correlation times of the Stokes shift dynamics match the longitudinal time constants of the system as derived from dielectric relaxation data. Additionally, a maximum of the time resolved optical linewidths is indicative of heterogeneous dynamics in the plastic crystal. The supercooled liquid state is obtained after quenching the liquid from room temperature to below Tg and displays relaxation times that are a factor of 100 faster compared with the plastic crystal at the same temperature. The results do not reveal different translational contributions to solvation for the two phases.
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U2 - 10.1088/0953-8984/15/32/304
DO - 10.1088/0953-8984/15/32/304
M3 - Article
AN - SCOPUS:0042413375
SN - 0953-8984
VL - 15
SP - 5429
EP - 5438
JO - Journal of Physics Condensed Matter
JF - Journal of Physics Condensed Matter
IS - 32
ER -