Solution synthesis of nanoparticular binary transition metal antimonides

Gregor Kieslich, Christina S. Birkel, Andrew Stewart, Ute Kolb, Wolfgang Tremel

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The preparation of nanoengineered materials with controlled nanostructures, for example, with an anisotropic phase segregated structure or a regular periodicity rather than with a broad range of interparticle distances, has remained a synthetic challenge for intermetallics. Artificially structured materials, including multilayers, amorphous alloys, quasicrystals, metastable crystalline alloys, or granular metals, are mostly prepared using physical gas phase procedures. We report a novel, powerful solution-mediated approach for the formation of nanoparticular binary antimonides based on presynthesized antimony nanoparticles. The transition metal antimonides M-Sb (M = Co, Ni, Cu 2, Zn) were obtained with sizes ranging from 20 and 60 nm. Through careful control of the reaction conditions, single-phase nanoparticular antimonides were synthesized. The nanophases were investigated by powder X-ray diffraction and (high resolution) electron microscopy. The approach is based on activated metal nanoparticles as precursors for the synthesis of the intermetallic compounds. X-ray powder diffraction studies of reaction intermediates allowed monitoring of the reaction kinetics. The small particle size of the reactants ensures short diffusion paths, low activation barriers, and low reaction temperatures, thereby eliminating solid-solid diffusion as the rate-limiting step in conventional bulk-scale solid-state synthesis.

Original languageEnglish (US)
Pages (from-to)6938-6943
Number of pages6
JournalInorganic chemistry
Volume50
Issue number15
DOIs
StatePublished - Aug 1 2011
Externally publishedYes

Fingerprint

antimonides
X ray powder diffraction
Intermetallics
Transition metals
transition metals
Diffusion in solids
Antimony
Reaction intermediates
Quasicrystals
intermetallics
Metal nanoparticles
High resolution electron microscopy
Amorphous alloys
synthesis
Phase structure
Reaction kinetics
Nanostructures
nanoparticles
Multilayers
reaction intermediates

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Solution synthesis of nanoparticular binary transition metal antimonides. / Kieslich, Gregor; Birkel, Christina S.; Stewart, Andrew; Kolb, Ute; Tremel, Wolfgang.

In: Inorganic chemistry, Vol. 50, No. 15, 01.08.2011, p. 6938-6943.

Research output: Contribution to journalArticle

Kieslich, Gregor ; Birkel, Christina S. ; Stewart, Andrew ; Kolb, Ute ; Tremel, Wolfgang. / Solution synthesis of nanoparticular binary transition metal antimonides. In: Inorganic chemistry. 2011 ; Vol. 50, No. 15. pp. 6938-6943.
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