Sol-gel synthesis of silicalite/γ-alumina granules

Zhaohui Yang, Y. S. Lin

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

Spherical silicalite/γ-Al2O3 composite granules of about 2 mm in diameter were prepared by a sol-gel process from a mixture of the stable boehmite and silicalite sols. The stable silicalite sol was prepared by a hydrothermal method. Silicalite/γ-Al2O3 composite granules with a zeolite content of up to 70 wt % were formed by the sol-gel 'oil-drop' process in which a paraffin oil and ammonia solution were used as the media to facilitate shape forming and consolidation of the gel structure. The sol-gel-derived silicalite/γ-Al2O3 granules have a pore structure reassembling that of a mixture of silicalite and γ-Al2O3 powders. The crush strength of the sol-gel-derived silicalite granules is about six times that of a similar commercial silicalite granule. In addition, the sol-gel-derived silicalite/γ-Al2O3 granules exhibit better sorption properties for SO2 at a lower SO2 partial pressure than pure silicalite powder.

Original languageEnglish (US)
Pages (from-to)4944-4948
Number of pages5
JournalIndustrial and Engineering Chemistry Research
Volume39
Issue number12
DOIs
StatePublished - Jan 1 2000
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

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