Slag characterization for the development of new and improved service life materials in gasifiers using flexible carbon feedstock

James Bennett, Seetharaman Sridhar, Jinichiro Nakano, Kyei Sing Kwong, Tom Lam, Tetsuya Kaneko, Laura Fernandez, Piyamanee Komolwit, Hugh Thomas, Rick Krabbe

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

In modern gasifiers, the carbon feedstock (coal, petcoke and/or biomass) is determined largely by carbon content, cost, availability, and environmental concerns. Ash impurities in the carbon feedstock vary widely in quantity and chemistry, impacting gasifier operation. Ash from mineral impurities in the feedstock liquefy at the elevated temperatures of gasification; impacting slag chemistry, viscosity, melting temperature, surface and interfacial tension - ultimately determining gasifier operating temperature and refractory service life. The slag itself experiences wide variations in the relative fraction and state of crystalline material (oxides, sulfides and metallic), non-crystalline (glass) material, or gas phases formed from feedstock ash. It is these variations that have a critical impact gasifier operation, determining slag fluidity along the walls and the chemical and physical stability (wear) of the refractory liner. In this paper, two aspects of joint research between NETL and CMU on slag and slag/refractory interactions will be discussed. The first area is researching phase formation in synthetic petcoke/coal slag (SiO 2-Al2O3-Fe2O3-CaO-V 2O3) under simulated gasification conditions (1500°C and 10-8 arm oxygen partial pressure). The second area focuses on interactions between coal and petcoke slags with commercial refractory currently used (high chrome oxide) or having the potential for use as a gasifier liner (high alumina). Refractory materials studied in the simulated gasifier environment were fired brick of the following compositions: 90wt%Cr 2O3-10wt%Al2O3 and 100wt%Al 2O3. Information from this research is being used to improve the performance of or to develop new refractory liner materials for gasifiers, and to understand mixed feedstock slag behavior under gasification conditions.

Original languageEnglish (US)
Title of host publicationAdvances in Materials Science for Environmental and Nuclear Technology II
Pages3-16
Number of pages14
StatePublished - 2011
Externally publishedYes
EventAdvances in Materials Science for Environmental and Nuclear Technology II - Materials Science and Technology 2010 Conference and Exhibition, MS and T'10 - Houston, TX, United States
Duration: Oct 17 2010Oct 21 2010

Publication series

NameCeramic Transactions
Volume227
ISSN (Print)1042-1122

Conference

ConferenceAdvances in Materials Science for Environmental and Nuclear Technology II - Materials Science and Technology 2010 Conference and Exhibition, MS and T'10
Country/TerritoryUnited States
CityHouston, TX
Period10/17/1010/21/10

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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