Single-crystal-to-single-crystal e → Z and Z → e isomerizations of 3-chloroacrylic acid within the nanocavities of a supramolecular framework

Shao Liang Zheng; Marc Messerschmidt; Philip Coppens

doi:10.1039/b703378h

Single-crystal-to-single-crystal e → Z and Z → e isomerizations of 3-chloroacrylic acid within the nanocavities of a supramolecular framework

Shao Liang Zheng, Marc Messerschmidt, Philip Coppens

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Single-crystal-to-single-crystal E → Z and Z → E photo-isomerizations of 3-chloroacrylic acid (HClA) take place with full retention of the crystal lattice in the framework cavities of the supramolecular crystals CECR·HClA·2MeOH·1.5H₂O (CECR = C-ethylcalix[4] resorcinarene); their progress has been monitored as the reaction proceeds.

Original language	English (US)
Pages (from-to)	2735-2737
Number of pages	3
Journal	Chemical Communications
Issue number	26
DOIs	https://doi.org/10.1039/b703378h
State	Published - Jan 1 2007
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Single-crystal-to-single-crystal E → Z and Z → E photo-isomerizations of 3-chloroacrylic acid (HClA) take place with full retention of the crystal lattice in the framework cavities of the supramolecular crystals CECR·HClA·2MeOH·1.5H2O (CECR = C-ethylcalix[4] resorcinarene); their progress has been monitored as the reaction proceeds.",

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AU - Messerschmidt, Marc

AU - Coppens, Philip

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AB - Single-crystal-to-single-crystal E → Z and Z → E photo-isomerizations of 3-chloroacrylic acid (HClA) take place with full retention of the crystal lattice in the framework cavities of the supramolecular crystals CECR·HClA·2MeOH·1.5H2O (CECR = C-ethylcalix[4] resorcinarene); their progress has been monitored as the reaction proceeds.

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Single-crystal-to-single-crystal e → Z and Z → e isomerizations of 3-chloroacrylic acid within the nanocavities of a supramolecular framework

Abstract

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