Shock-formed carbon materials with intergrown sp3- and sp2-bonded nanostructured units

Péter Németh, Hector J. Lancaster, Christoph G. Salzmann, Kit McColl, Zsolt Fogarassy, Laurence A.J. Garvie, Levente Illés, Béla Pécz, Mara Murri, Furio Corá, Rachael L. Smith, Mohamed Mezouar, Christopher A. Howard, Paul F. McMillan

Research output: Contribution to journalArticlepeer-review

Abstract

Studies of dense carbon materials formed by bolide impacts or produced by laboratory compression provide key information on the high-pressure behavior of carbon and for identifying and designing unique structures for technological applications. However, a major obstacle to studying and designing these materials is an incomplete understanding of their fundamental structures. Here, we report the remarkable structural diversity of cubic/hexagonally (c/h) stacked diamond and their association with diamond-graphite nanocomposites containing sp3-/sp2-bonding patterns, i.e., diaphites, from hard carbon materials formed by shock impact of graphite in the Canyon Diablo iron meteorite. We show evidence for a range of intergrowth types and nanostructures containing unusually short (0.31 nm) graphene spacings and demonstrate that previously neglected or misinterpreted Raman bands can be associated with diaphite structures. Our study provides a structural understanding of the material known as lonsdaleite, previously described as hexagonal diamond, and extends this understanding to other natural and synthetic ultrahard carbon phases. The unique three-dimensional carbon architectures encountered in shock-formed samples can place constraints on the pressure–temperature conditions experienced during an impact and provide exceptional opportunities to engineer the properties of carbon nanocomposite materials and phase assemblages.

Original languageEnglish (US)
Article numbere2203672119
JournalProceedings of the National Academy of Sciences of the United States of America
Volume119
Issue number30
DOIs
StatePublished - Jul 26 2022

Keywords

  • cubic/hexagonally stacked diamond
  • diaphite
  • shock-formed carbon
  • ultrahard material

ASJC Scopus subject areas

  • General

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