Selective CO2 capture in an imine linked porphyrin porous polymer

Venkata S.Pavan K. Neti; Xiaofei Wu; Shuguang Deng; Luis Echegoyen

doi:10.1039/c3py00798g

Selective CO₂ capture in an imine linked porphyrin porous polymer

Venkata S.Pavan K. Neti, Xiaofei Wu, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

A new microporous imine-linked porous porphyrin polymer, CuPor-BPDC, has been solvothermally synthesized. The CuPor-BPDC showed high CO₂ capture (5.5 wt% at 273 K/1 bar) and very good selectivity for CO ₂/CH₄ adsorption (5.6) at 1.0 bar and 273 K, and exhibited a BET surface area of 442 m² g^-1 with high thermal stability (up to 400°C), thus showing good potential for CO₂ capture.

Original language	English (US)
Pages (from-to)	4566-4569
Number of pages	4
Journal	Polymer Chemistry
Volume	4
Issue number	17
DOIs	https://doi.org/10.1039/c3py00798g
State	Published - 2013
Externally published	Yes

ASJC Scopus subject areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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abstract = "A new microporous imine-linked porous porphyrin polymer, CuPor-BPDC, has been solvothermally synthesized. The CuPor-BPDC showed high CO2 capture (5.5 wt% at 273 K/1 bar) and very good selectivity for CO 2/CH4 adsorption (5.6) at 1.0 bar and 273 K, and exhibited a BET surface area of 442 m2 g-1 with high thermal stability (up to 400°C), thus showing good potential for CO2 capture.",

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AU - Neti, Venkata S.Pavan K.

AU - Wu, Xiaofei

AU - Deng, Shuguang

AU - Echegoyen, Luis

PY - 2013

Y1 - 2013

N2 - A new microporous imine-linked porous porphyrin polymer, CuPor-BPDC, has been solvothermally synthesized. The CuPor-BPDC showed high CO2 capture (5.5 wt% at 273 K/1 bar) and very good selectivity for CO 2/CH4 adsorption (5.6) at 1.0 bar and 273 K, and exhibited a BET surface area of 442 m2 g-1 with high thermal stability (up to 400°C), thus showing good potential for CO2 capture.

AB - A new microporous imine-linked porous porphyrin polymer, CuPor-BPDC, has been solvothermally synthesized. The CuPor-BPDC showed high CO2 capture (5.5 wt% at 273 K/1 bar) and very good selectivity for CO 2/CH4 adsorption (5.6) at 1.0 bar and 273 K, and exhibited a BET surface area of 442 m2 g-1 with high thermal stability (up to 400°C), thus showing good potential for CO2 capture.

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JO - Polymer Chemistry

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Selective CO₂ capture in an imine linked porphyrin porous polymer

Abstract

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