Selective CO2 adsorption in a porphyrin polymer with benzimidazole linkages

Venkata S.Pavan K. Neti, Jun Wang, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journalArticle

17 Scopus citations

Abstract

A new nanoporous porphyrin-based benzimidazole linked polymer, PBILP, was synthesized. The use of porphyrin monomers as molecular building units led to the formation of a rigid amorphous network that has a moderate surface area (SBET = 557 m2 g-1). The CO2 adsorption ability of PBILP is 12.1 wt% (2.76 mmol g-1) and it has a CO2/CH4 selectivity of 7.2 at 273 K/1 bar and a CO2/N2 selectivity of 72 at 273 K/1 bar.

Original languageEnglish (US)
Pages (from-to)10960-10963
Number of pages4
JournalRSC Advances
Volume5
Issue number15
DOIs
StatePublished - 2015
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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