TY - JOUR
T1 - Selecting metal oxide nanomaterials for arsenic removal in fixed bed columns
T2 - From nanopowders to aggregated nanoparticle media
AU - Hristovski, Kiril
AU - Baumgardner, Andrew
AU - Westerhoff, Paul
N1 - Funding Information:
The study was conducted with support from AWWARF Project #3077, DOW Chemicals, Hydroglobe/Grover Technologies, and the Environmental Technology Laboratory at Arizona State University Polytechnic Campus.
Copyright:
Copyright 2009 Elsevier B.V., All rights reserved.
PY - 2007/8/17
Y1 - 2007/8/17
N2 - This paper investigates the feasibility of arsenate removal by aggregated metal oxide nanoparticle media in packed bed columns. Batch experiments conducted with 16 commercial nanopowders in four water matrices were used to select a metal oxide nanoparticle that both amply removes arsenate and can be aggregated using an inert binder. TiO2, Fe2O3, ZrO2 and NiO nanopowders, which exhibited the highest arsenate removal in all water matrices, were characterized with fitted Freundlich adsorption isotherm (q = K Ce1 / n) parameters. In 10 mM NaHCO3 buffered nanopure water and at both pH ≈ 6.7 and 8.4, K ranged from 1.3 to 12.09 (mg As/g(media)) (L/mg As)1/n, and 1/n ranged from 0.21 to 0.52. Under these conditions, the fitted Freundlich isotherm parameters for TiO2 nanoparticles aggregated with inorganic and organic binders (K of 4.75-28.45 (mg As/g(media)) (L/mg As)1/n and 1/n of 0.37-0.97) suggested favorable arsenate adsorption. To demonstrate that aggregated nanoparticle media would allow rapid mass transport of arsenate in a fixed bed adsorber setting, short bed adsorber (SBA) tests were conducted on TiO2 nanoparticle aggregates at empty bed contact times (EBCT) of 0.1-0.5 min and Re × Sc = 1000 and 2000. These SBA tests suggested that the binder has a negligible role in adsorbing arsenic and that mass transport is controlled by rapid intraparticle diffusion rather than external film diffusion.
AB - This paper investigates the feasibility of arsenate removal by aggregated metal oxide nanoparticle media in packed bed columns. Batch experiments conducted with 16 commercial nanopowders in four water matrices were used to select a metal oxide nanoparticle that both amply removes arsenate and can be aggregated using an inert binder. TiO2, Fe2O3, ZrO2 and NiO nanopowders, which exhibited the highest arsenate removal in all water matrices, were characterized with fitted Freundlich adsorption isotherm (q = K Ce1 / n) parameters. In 10 mM NaHCO3 buffered nanopure water and at both pH ≈ 6.7 and 8.4, K ranged from 1.3 to 12.09 (mg As/g(media)) (L/mg As)1/n, and 1/n ranged from 0.21 to 0.52. Under these conditions, the fitted Freundlich isotherm parameters for TiO2 nanoparticles aggregated with inorganic and organic binders (K of 4.75-28.45 (mg As/g(media)) (L/mg As)1/n and 1/n of 0.37-0.97) suggested favorable arsenate adsorption. To demonstrate that aggregated nanoparticle media would allow rapid mass transport of arsenate in a fixed bed adsorber setting, short bed adsorber (SBA) tests were conducted on TiO2 nanoparticle aggregates at empty bed contact times (EBCT) of 0.1-0.5 min and Re × Sc = 1000 and 2000. These SBA tests suggested that the binder has a negligible role in adsorbing arsenic and that mass transport is controlled by rapid intraparticle diffusion rather than external film diffusion.
KW - Arsenic
KW - Fixed bed column
KW - Metal oxide
KW - Nanoparticle
KW - Water
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U2 - 10.1016/j.jhazmat.2007.01.017
DO - 10.1016/j.jhazmat.2007.01.017
M3 - Article
C2 - 17254707
AN - SCOPUS:34447644388
SN - 0304-3894
VL - 147
SP - 265
EP - 274
JO - Journal of Hazardous Materials
JF - Journal of Hazardous Materials
IS - 1-2
ER -