Seifertite, a dense orthorhombic polymorph of silica from the Martian meteorites Shergotty and Zagami

Ahmed El Goresy, Przemyslaw Dera, Thomas Sharp, Charles T. Prewitt, Ming Chen, Leonid Dubrovinsky, Brigitte Wopenka, Nabil Z. Boctor, Russell J. Hemley

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Seifertite is a dense orthorhombic polymorph of silica with the scrutinyite (α-PbO2) type structure that was found as lamellae occurring together with dense silica glass lamellae in composite silica grains in the heavily shocked Martian meteorite Shergotty. The mineral is also intergrown in some grains with minor stishovite and a new unnamed monoclinic dense silica polymorph with a ZrO2-type structure. Scifertite has also been found in the Martian shergottite Zagami and is a minor constituent in other Martian shergottites. Chemical analyses of seifertite in Shergotty indicate major SiO2 with minor concentrations of Al2O3 and Na2O, Selected-area electron diffraction (SAED) and X-ray diffraction can be interpreted in terms of an orthorhombic pattern from a scrutinyite (α-PbO2) structure. The cell parameters are α = 4.097(1) Å, b = 5.0462(9) Å, c = 4.4946(8) Å, V = 92.92 Å3, Z = 4, and the space group is Pbcn or Pb2n. Density is (calc.) = 4.294 g/cm3 (with pure SiO2), 4.309 g/cm3 (with empirical formula). It is inferred that seifertite was formed by shock-induced solid-state transformation of either tridymite or cristobalite on Mars at an estimated minimum equilibrium shock pressure in excess of 35 GPa. The new mineral is named after Friedrich A. Seifert (b. 1941), founding. Director of the Bayerisches Geoinstitut, Universität Bayreuth, Germany, for his seminal contributions to high-pressure geoscience.

Original languageEnglish (US)
Pages (from-to)523-528
Number of pages6
JournalEuropean Journal of Mineralogy
Volume20
Issue number4
DOIs
StatePublished - Jul 2008

Fingerprint

Meteorites
Martian meteorite
Polymorphism
Silicon Dioxide
silica
shergottite
Minerals
tridymite
stishovite
cristobalite
new mineral
diffraction
Mars
Fused silica
Electron diffraction
glass
X-ray diffraction
electron
mineral
X ray diffraction

Keywords

  • αPbO structure type
  • High-pressure phases
  • New mineral
  • Seifertite
  • Shergotty meteorite
  • Shock metamorphism
  • Silica

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

Seifertite, a dense orthorhombic polymorph of silica from the Martian meteorites Shergotty and Zagami. / El Goresy, Ahmed; Dera, Przemyslaw; Sharp, Thomas; Prewitt, Charles T.; Chen, Ming; Dubrovinsky, Leonid; Wopenka, Brigitte; Boctor, Nabil Z.; Hemley, Russell J.

In: European Journal of Mineralogy, Vol. 20, No. 4, 07.2008, p. 523-528.

Research output: Contribution to journalArticle

El Goresy, A, Dera, P, Sharp, T, Prewitt, CT, Chen, M, Dubrovinsky, L, Wopenka, B, Boctor, NZ & Hemley, RJ 2008, 'Seifertite, a dense orthorhombic polymorph of silica from the Martian meteorites Shergotty and Zagami', European Journal of Mineralogy, vol. 20, no. 4, pp. 523-528. https://doi.org/10.1127/0935-1221/2008/0020-1812
El Goresy, Ahmed ; Dera, Przemyslaw ; Sharp, Thomas ; Prewitt, Charles T. ; Chen, Ming ; Dubrovinsky, Leonid ; Wopenka, Brigitte ; Boctor, Nabil Z. ; Hemley, Russell J. / Seifertite, a dense orthorhombic polymorph of silica from the Martian meteorites Shergotty and Zagami. In: European Journal of Mineralogy. 2008 ; Vol. 20, No. 4. pp. 523-528.
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abstract = "Seifertite is a dense orthorhombic polymorph of silica with the scrutinyite (α-PbO2) type structure that was found as lamellae occurring together with dense silica glass lamellae in composite silica grains in the heavily shocked Martian meteorite Shergotty. The mineral is also intergrown in some grains with minor stishovite and a new unnamed monoclinic dense silica polymorph with a ZrO2-type structure. Scifertite has also been found in the Martian shergottite Zagami and is a minor constituent in other Martian shergottites. Chemical analyses of seifertite in Shergotty indicate major SiO2 with minor concentrations of Al2O3 and Na2O, Selected-area electron diffraction (SAED) and X-ray diffraction can be interpreted in terms of an orthorhombic pattern from a scrutinyite (α-PbO2) structure. The cell parameters are α = 4.097(1) {\AA}, b = 5.0462(9) {\AA}, c = 4.4946(8) {\AA}, V = 92.92 {\AA}3, Z = 4, and the space group is Pbcn or Pb2n. Density is (calc.) = 4.294 g/cm3 (with pure SiO2), 4.309 g/cm3 (with empirical formula). It is inferred that seifertite was formed by shock-induced solid-state transformation of either tridymite or cristobalite on Mars at an estimated minimum equilibrium shock pressure in excess of 35 GPa. The new mineral is named after Friedrich A. Seifert (b. 1941), founding. Director of the Bayerisches Geoinstitut, Universit{\"a}t Bayreuth, Germany, for his seminal contributions to high-pressure geoscience.",
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T1 - Seifertite, a dense orthorhombic polymorph of silica from the Martian meteorites Shergotty and Zagami

AU - El Goresy, Ahmed

AU - Dera, Przemyslaw

AU - Sharp, Thomas

AU - Prewitt, Charles T.

AU - Chen, Ming

AU - Dubrovinsky, Leonid

AU - Wopenka, Brigitte

AU - Boctor, Nabil Z.

AU - Hemley, Russell J.

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N2 - Seifertite is a dense orthorhombic polymorph of silica with the scrutinyite (α-PbO2) type structure that was found as lamellae occurring together with dense silica glass lamellae in composite silica grains in the heavily shocked Martian meteorite Shergotty. The mineral is also intergrown in some grains with minor stishovite and a new unnamed monoclinic dense silica polymorph with a ZrO2-type structure. Scifertite has also been found in the Martian shergottite Zagami and is a minor constituent in other Martian shergottites. Chemical analyses of seifertite in Shergotty indicate major SiO2 with minor concentrations of Al2O3 and Na2O, Selected-area electron diffraction (SAED) and X-ray diffraction can be interpreted in terms of an orthorhombic pattern from a scrutinyite (α-PbO2) structure. The cell parameters are α = 4.097(1) Å, b = 5.0462(9) Å, c = 4.4946(8) Å, V = 92.92 Å3, Z = 4, and the space group is Pbcn or Pb2n. Density is (calc.) = 4.294 g/cm3 (with pure SiO2), 4.309 g/cm3 (with empirical formula). It is inferred that seifertite was formed by shock-induced solid-state transformation of either tridymite or cristobalite on Mars at an estimated minimum equilibrium shock pressure in excess of 35 GPa. The new mineral is named after Friedrich A. Seifert (b. 1941), founding. Director of the Bayerisches Geoinstitut, Universität Bayreuth, Germany, for his seminal contributions to high-pressure geoscience.

AB - Seifertite is a dense orthorhombic polymorph of silica with the scrutinyite (α-PbO2) type structure that was found as lamellae occurring together with dense silica glass lamellae in composite silica grains in the heavily shocked Martian meteorite Shergotty. The mineral is also intergrown in some grains with minor stishovite and a new unnamed monoclinic dense silica polymorph with a ZrO2-type structure. Scifertite has also been found in the Martian shergottite Zagami and is a minor constituent in other Martian shergottites. Chemical analyses of seifertite in Shergotty indicate major SiO2 with minor concentrations of Al2O3 and Na2O, Selected-area electron diffraction (SAED) and X-ray diffraction can be interpreted in terms of an orthorhombic pattern from a scrutinyite (α-PbO2) structure. The cell parameters are α = 4.097(1) Å, b = 5.0462(9) Å, c = 4.4946(8) Å, V = 92.92 Å3, Z = 4, and the space group is Pbcn or Pb2n. Density is (calc.) = 4.294 g/cm3 (with pure SiO2), 4.309 g/cm3 (with empirical formula). It is inferred that seifertite was formed by shock-induced solid-state transformation of either tridymite or cristobalite on Mars at an estimated minimum equilibrium shock pressure in excess of 35 GPa. The new mineral is named after Friedrich A. Seifert (b. 1941), founding. Director of the Bayerisches Geoinstitut, Universität Bayreuth, Germany, for his seminal contributions to high-pressure geoscience.

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KW - Shergotty meteorite

KW - Shock metamorphism

KW - Silica

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