TY - JOUR
T1 - Second cross virial coefficients for interactions involving water. Critical data compilation
AU - Plyasunov, Andrey V.
AU - Shock, Everett
PY - 2003/7
Y1 - 2003/7
N2 - Values of the second cross virial coefficients, B12, and isothermal Joule-Thomson coefficients, φ12, for interactions involving water are compiled and, as necessary, evaluated from existing experimental data including PVT properties of gas mixtures, measurements of the pressure dependence of the molar excess enthalpies of a gas mixture, and measurements of the solubility of the condensed phases of H2O (liquid water or ice) in compressed gases. In all, there are data for interactions between water and 32 other compounds, and among these, nine interactions involve compounds with appreciable dipole moments. These B12 values, typically available over a limited temperature range, are extrapolated to high temperatures by means of the Tsonopoulos corresponding-states correlation. Finally, the temperature dependence of the second cross virial coefficients between water and solutes at temperatures up to 1200 K is approximated by an empirical polynomial equation, the coefficients of which are tabulated for each interaction.
AB - Values of the second cross virial coefficients, B12, and isothermal Joule-Thomson coefficients, φ12, for interactions involving water are compiled and, as necessary, evaluated from existing experimental data including PVT properties of gas mixtures, measurements of the pressure dependence of the molar excess enthalpies of a gas mixture, and measurements of the solubility of the condensed phases of H2O (liquid water or ice) in compressed gases. In all, there are data for interactions between water and 32 other compounds, and among these, nine interactions involve compounds with appreciable dipole moments. These B12 values, typically available over a limited temperature range, are extrapolated to high temperatures by means of the Tsonopoulos corresponding-states correlation. Finally, the temperature dependence of the second cross virial coefficients between water and solutes at temperatures up to 1200 K is approximated by an empirical polynomial equation, the coefficients of which are tabulated for each interaction.
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U2 - 10.1021/je034046u
DO - 10.1021/je034046u
M3 - Article
AN - SCOPUS:0041807561
SN - 0021-9568
VL - 48
SP - 808
EP - 821
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 4
ER -