Rotational Analysis of the A4Πr-X4Σ- Band System of Molybdenum Nitride (MoN)

K. Y. Jung; D. A. Fletcher; Timothy Steimle

doi:10.1006/jmsp.1994.1147

Rotational Analysis of the A⁴Π_r-X⁴Σ^- Band System of Molybdenum Nitride (MoN)

K. Y. Jung, D. A. Fletcher, Timothy Steimle

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The high-resolution laser-induced fluorescence spectrum of a supersonic molecular beam sample of molybdenum nitride, MoN, was recorded in the 596- to 633-nm spectral range. The A⁴Π_r-X⁴Σ^- band system of the ⁹²Mo, ⁹⁴Mo, ⁹⁶Mo, ⁹⁸Mo, and ¹⁰⁰Mo isotopic forms was analyzed to produce an improved set of spectroscopic parameters. The isotopic dependence of the parameters is discussed and a comparison with a previous rotational analysis is given.

Original language	English (US)
Pages (from-to)	448-456
Number of pages	9
Journal	Journal of molecular spectroscopy
Volume	165
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.1994.1147
State	Published - Jun 1 1994

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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abstract = "The high-resolution laser-induced fluorescence spectrum of a supersonic molecular beam sample of molybdenum nitride, MoN, was recorded in the 596- to 633-nm spectral range. The A4Πr-X4Σ- band system of the 92Mo, 94Mo, 96Mo, 98Mo, and 100Mo isotopic forms was analyzed to produce an improved set of spectroscopic parameters. The isotopic dependence of the parameters is discussed and a comparison with a previous rotational analysis is given.",

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AB - The high-resolution laser-induced fluorescence spectrum of a supersonic molecular beam sample of molybdenum nitride, MoN, was recorded in the 596- to 633-nm spectral range. The A4Πr-X4Σ- band system of the 92Mo, 94Mo, 96Mo, 98Mo, and 100Mo isotopic forms was analyzed to produce an improved set of spectroscopic parameters. The isotopic dependence of the parameters is discussed and a comparison with a previous rotational analysis is given.

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Rotational Analysis of the A⁴Π_r-X⁴Σ^- Band System of Molybdenum Nitride (MoN)

Abstract

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