Room temperature 3D printing of super-soft and solvent-free elastomers

Renxuan Xie, Sanjoy Mukherjee, Adam E. Levi, Veronica G. Reynolds, Hengbin Wang, Michael L. Chabinyc, Christopher M. Bates

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Super-soft elastomers derived from bottlebrush polymers show promise as advanced materials for biomimetic tissue and device applications, but current processing strategies are restricted to simple molding. Here, we introduce a design concept that enables the three-dimensional (3D) printing of super-soft and solvent-free bottlebrush elastomers at room temperature. The key advance is a class of inks comprising statistical bottlebrush polymers that self-assemble into well-ordered body-centered cubic sphere phases. These soft solids undergo sharp and reversible yielding at 20°C in response to shear with a yield stress that can be tuned by manipulating the length scale of microphase separation. The addition of a soluble photocrosslinker allows complete ultraviolet curing after extrusion to form super-soft elastomers with near-perfect recoverable elasticity well beyond the yield strain. These structure- property design rules create exciting opportunities to tailor the performance of 3D-printed elastomers in ways that are not possible with current materials and processes.

Original languageEnglish (US)
Article numbereabc6900
JournalScience Advances
Volume6
Issue number46
DOIs
StatePublished - Nov 13 2020
Externally publishedYes

ASJC Scopus subject areas

  • General

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