Abstract
A study is conducted to describe a one-step synthetic approach using NMP to prepare network polymers with dynamic alkoxyamine crosslinks that allows for reprocessing in the melt state through repeated bond formation and dissociation. With this method, we use stable nitroxide radicals containing a polymerizing moiety as both radical regulators during reaction and branch units on the polymers or crosslinker chains. The study also uses bifunctional initiators to generate chains with radical sites on both sides to connect the nitroxide branch units, resulting in crosslinked polymer.
Original language | English (US) |
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Pages (from-to) | 6746-6750 |
Number of pages | 5 |
Journal | Advanced Materials |
Volume | 28 |
Issue number | 31 |
DOIs | |
State | Published - Aug 2016 |
Externally published | Yes |
Keywords
- compression molding
- dynamic covalent bonds
- nitroxide-mediated polymerization
- recyclable crosslinked polymers
- uniform polymer networks
ASJC Scopus subject areas
- General Materials Science
- Mechanics of Materials
- Mechanical Engineering