Recent results on the connection between thermodynamics and dynamics in supercooled water

Francis W. Starr, Charles Angell, Emilia La Nave, Srikanth Sastry, Antonio Scala, Francesco Sciortino, H. Eugene Stanley

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16 Scopus citations

Abstract

We review recent results on the connection between thermodynamics and dynamics in a model for water. We verify the Adam-Gibbs relation between entropy and dynamic properties using computer simulations, which allow direct access to the relevant properties. We combine experimental measurements of entropy with the Adam-Gibbs hypothesis to predict dynamic properties in deeply supercooled states, which are difficult to access experimentally. We find evidence suggesting that the glass transition temperature of water may be significantly higher than previously reported, but is still consistent with recent measurements. Finally, we discuss the hypothesis that the dynamical behavior of deeply supercooled water undergoes a crossover from 'fragile' to 'strong' behavior.

Original languageEnglish (US)
Pages (from-to)573-583
Number of pages11
JournalBiophysical Chemistry
Volume105
Issue number2-3
DOIs
StatePublished - Sep 1 2003

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Keywords

  • Experimentally
  • Fragile
  • Hypothesis
  • Thermodynamics

ASJC Scopus subject areas

  • Biophysics
  • Biochemistry
  • Organic Chemistry

Cite this

Starr, F. W., Angell, C., La Nave, E., Sastry, S., Scala, A., Sciortino, F., & Stanley, H. E. (2003). Recent results on the connection between thermodynamics and dynamics in supercooled water. Biophysical Chemistry, 105(2-3), 573-583. https://doi.org/10.1016/S0301-4622(03)00067-X