Reaction kinetics in sodium silicate powder and liquid activated slag binders evaluated using isothermal calorimetry

Deepak Ravikumar, Narayanan Neithalath

Research output: Contribution to journalArticle

61 Citations (Scopus)

Abstract

The kinetics of alkali activation of slag is highly dependent on the activator type and its chemical constitution. This paper explores the early-age reaction kinetics of slag activated using powder sodium silicate (which makes handling easier in practice) and compares it with that of waterglass (liquid sodium silicate) activated slag pastes. The influence of Na 2O-to-slag ratio and the activator modulus (SiO 2-to-Na 2O ratio) on the isothermal calorimetric response is presented. The powder sodium silicate activated slag pastes show a calorimetric response similar to NaOH activated slag systems, with both demonstrating single early-age reaction peaks. In contrast, the waterglass activated systems show a calorimetric response similar to those of OPC pastes, with a marked induction period. Kinetic modeling is used to quantify the differences in reaction kinetics. Jander equation is used to model the time-dependent degree of reaction and to relate it to the rate controlling processes when different types of activators are used.

Original languageEnglish (US)
Pages (from-to)32-43
Number of pages12
JournalThermochimica Acta
Volume546
DOIs
StatePublished - Oct 20 2012

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sodium silicates
slags
Calorimetry
Reaction kinetics
Powders
Slags
Silicates
Binders
reaction kinetics
heat measurement
Sodium
Liquids
liquids
Ointments
liquid sodium
Kinetics
constitution
kinetics
Alkalies
sodium silicate

Keywords

  • Alkali activation
  • Isothermal calorimetry
  • Kinetic modeling
  • Reaction kinetics
  • Slag
  • Sodium silicate

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Instrumentation

Cite this

Reaction kinetics in sodium silicate powder and liquid activated slag binders evaluated using isothermal calorimetry. / Ravikumar, Deepak; Neithalath, Narayanan.

In: Thermochimica Acta, Vol. 546, 20.10.2012, p. 32-43.

Research output: Contribution to journalArticle

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AB - The kinetics of alkali activation of slag is highly dependent on the activator type and its chemical constitution. This paper explores the early-age reaction kinetics of slag activated using powder sodium silicate (which makes handling easier in practice) and compares it with that of waterglass (liquid sodium silicate) activated slag pastes. The influence of Na 2O-to-slag ratio and the activator modulus (SiO 2-to-Na 2O ratio) on the isothermal calorimetric response is presented. The powder sodium silicate activated slag pastes show a calorimetric response similar to NaOH activated slag systems, with both demonstrating single early-age reaction peaks. In contrast, the waterglass activated systems show a calorimetric response similar to those of OPC pastes, with a marked induction period. Kinetic modeling is used to quantify the differences in reaction kinetics. Jander equation is used to model the time-dependent degree of reaction and to relate it to the rate controlling processes when different types of activators are used.

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