Rapid synthesis of crystalline spinel tin nitride by a solid-state metathesis reaction

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Abstract

Spinel tin nitride (Sn3N4) was prepared by high-pressure solid-state metathesis reactions. Tin tetraiodide was reacted with lithium nitride and ammonium chloride in a piston-cylinder apparatus at 623 K and 2.5 GPa. Powder X-ray diffraction combined with Rietveld refinement confirmed the spinel structure, with a lattice constant of a = 9.0144(1) Å. Raman spectroscopy revealed five active vibrational modes at 160, 252, 416, 524, and 622 cm-1, which are consistent with the spinel structure. Mid-infrared spectroscopy exhibited only a Sn-N stretching mode at 547 cm-1. Transmission electron microscopy was used to reveal particle size and morphology. Electron probe microanalysis was used to verify the elemental composition.

Original languageEnglish (US)
Pages (from-to)101-104
Number of pages4
JournalJournal of the American Ceramic Society
Volume85
Issue number1
StatePublished - Jan 1 2002

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ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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